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      Experimental estimation of the settling velocity and drag coefficient of the hollow cylindrical particles settling in non‐Newtonian fluids in an annular channel

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      The Canadian Journal of Chemical Engineering
      Wiley

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          Abstract

          The drag coefficient data of particles settling in an annular channel is very much essential for designing different solid–fluid handling equipment, such as the fluidized bed. Experimental settling velocity, wall factor, and drag coefficient data of the hollow‐cylinder particle are presented. Carboxymethyl cellulose solution has been used as the working fluid with a flow index of 0.64 ≤ n ≤ 0.91 and a consistency index of 0.31 ≤ K ≤ 1.81. The experimental results covered a wide diameter ratio range (0.14 ≤ d eq /L ≤ 0.46), hollow cylinder inner to outer diameter ratio (0.2 ≤ d i /d o ≤0.8), and Reynolds number (0.05 ≤ Re ≤ 51 and 0.09 ≤ Re ≤ 55). d eq , d i , and d o are the equivalent inner and outer diameters of the particle, L is the annular gap, and Re and Re are the Reynolds numbers in the presence and absence of the wall effect, respectively. The wall factor decreased, and the drag coefficient increased with d eq /L and d i /d o ratios. The above parameters declined with the Reynolds number. The hollow cylinder experienced a lesser wall effect than the spherical particles settling in a non‐annular channel. In some cases, the wall factor of the hollow cylinder is found to be equal to the spherical particles settling in an annular channel. The developed correlations have successfully predicted the drag coefficients of the hollow cylinder.

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          TiO2-Assisted Degradation of Environmentally Relevant Organic Compounds in Wastewater Using a Novel Fluidized Bed Photoreactor

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            Settling Velocity of Irregularly Shaped Particles

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              Is Open Access

              A fluidized-bed reactor for the photocatalytic mineralization of phenol on TiO 2 -coated silica gel

              TiO2 photocatalysis represents a promising class of oxidation techniques that are intended to be both supplementary and complementary to the conventional approaches for the removal of refractory and trace organic contaminants in water and air. Powdered TiO2 dispersion systems employed in most studies require an additional separation step to recover the catalyst from the effluent water, which represents a major drawback for large scale applications. The optimization of photocatalytic treatment systems involves merging the benefits of catalyst immobilization on a retainable support, thus eliminating the need for downstream catalyst separation, maximization of photon-exposed catalyst area, and continuous operation. Aiming to integrate such conditions into a single system, a bench-scale annular photo-reactor with concentric UV-C lamp was built to study the photocatalytic mineralization of phenol on fluidized silica gel beads coated with sol-gel-synthetized TiO2. Reactor efficiency was investigated for different silica particle diameters (224, 357 and 461 μm), fluidized-bed concentrations in the bulk liquid (5, 10, 20 and 30 g L−1), initial phenol concentrations in the aqueous solution (0.25 mmol L−1 to 4.0 mmol L−1), and single and multiple sol-gel depositions. Then, the resulting optimum reactor configuration was compared to that of the same process on suspended Degussa P25 TiO2 nanoparticles under similar experimental conditions. The latter is expected to be more efficient, but post-treatment catalyst recovery, being an energy intensive process, represents a major limitation for large scale applications. Process efficiency was measured as a function of the accumulated energy necessary for the mineralization of 50% of the initial dissolved chemical oxygen demand (COD), or, Q0.5. Results showed that for any given mass of fluidized bed material, photo-oxidation efficiency increases with decreasing particle size (even for bed concentrations with similar equivalent surface area), decreasing initial phenol concentrations, and increasing number of sol-gel coatings. It was found that, for any given particle size and contaminant mass, there is an optimum bed concentration of 20 g L−1 for which Q0.5 reaches a minimum. Finally, under the optimum configuration, the fluidized-bed reactor efficiency is only 30% lower than that of photocatalysis on suspended TiO2 nanopowder, thus making the proposed fluidized system a viable alternative to slurry-TiO2 reactors.
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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                The Canadian Journal of Chemical Engineering
                Can J Chem Eng
                Wiley
                0008-4034
                1939-019X
                November 2023
                April 02 2023
                November 2023
                : 101
                : 11
                : 6632-6640
                Affiliations
                [1 ] Laboratory of Transport Phenomenon Department of Chemical Engineering, NIT Rourkela Rourkela Odisha 769008 India
                Article
                10.1002/cjce.24909
                93d79b5b-af9b-4bf2-b037-bfbe7705fedb
                © 2023

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