The 21st century is the information age. The ever-changing information technology not only affects the development of the global economy, but also has an important impact on the field of education and personnel training. Under the influence of information technology, the way people acquire, impart, and evaluate knowledge has changed greatly. The educational concepts, models, and methods of the new era are fundamentally different from traditional education, which provides new opportunities and new challenges for the education and teaching work of contemporary teachers. This paper aims to discuss the application of augmented reality technology in volleyball teaching, and give an effective method for AR to be applied to volleyball teaching. In this paper, the existing AR teaching system has the problem of poor transmission rate and cannot cooperate with volleyball teaching well. Therefore, a wireless communication auxiliary algorithm based on intelligent reflective surface is proposed. And the current situation of volleyball teaching is investigated and analyzed. And in response to the survey results, 78% of the students supported teachers in applying AR technology to assist teaching in volleyball teaching classes. This fully shows that there is still a lot of application space for AR technology in current volleyball teaching.