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      Graphitic Dots Combining Photophysical Characteristics of Organic Molecular Fluorophores and Inorganic Quantum Dots

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          Abstract

          Thanks to their photophysical properties, both organic molecular fluorophores (MFs) and inorganic quantum dots (QDs) are extensively used for bioimaging applications. However, limitations such as photobleaching for the former or blinking, size, and toxicity for the latter still constitute a challenge for numerous applications. We report here that embedding MFs in graphitic carbon dots (GDs) results in fluorophores which entirely tackle this challenge. Characterized by ultranarrow, bright, and excitation-independent emission devoid of blinking and photobleaching, these hybrid-featured nanoparticles also demonstrate their unique photophysical performances at the single-nanoparticle scale, making them appealing candidates for bioimaging applications.

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          Solution-processed, high-performance light-emitting diodes based on quantum dots.

          Solution-processed optoelectronic and electronic devices are attractive owing to the potential for low-cost fabrication of large-area devices and the compatibility with lightweight, flexible plastic substrates. Solution-processed light-emitting diodes (LEDs) using conjugated polymers or quantum dots as emitters have attracted great interest over the past two decades. However, the overall performance of solution-processed LEDs--including their efficiency, efficiency roll-off at high current densities, turn-on voltage and lifetime under operational conditions-remains inferior to that of the best vacuum-deposited organic LEDs. Here we report a solution-processed, multilayer quantum-dot-based LED with excellent performance and reproducibility. It exhibits colour-saturated deep-red emission, sub-bandgap turn-on at 1.7 volts, high external quantum efficiencies of up to 20.5 per cent, low efficiency roll-off (up to 15.1 per cent of the external quantum efficiency at 100 mA cm(-2)), and a long operational lifetime of more than 100,000 hours at 100 cd m(-2), making this device the best-performing solution-processed red LED so far, comparable to state-of-the-art vacuum-deposited organic LEDs. This optoelectronic performance is achieved by inserting an insulating layer between the quantum dot layer and the oxide electron-transport layer to optimize charge balance in the device and preserve the superior emissive properties of the quantum dots. We anticipate that our results will be a starting point for further research, leading to high-performance, all-solution-processed quantum-dot-based LEDs ideal for next-generation display and solid-state lighting technologies.
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            Nanometre-scale thermometry in a living cell.

            Sensitive probing of temperature variations on nanometre scales is an outstanding challenge in many areas of modern science and technology. In particular, a thermometer capable of subdegree temperature resolution over a large range of temperatures as well as integration within a living system could provide a powerful new tool in many areas of biological, physical and chemical research. Possibilities range from the temperature-induced control of gene expression and tumour metabolism to the cell-selective treatment of disease and the study of heat dissipation in integrated circuits. By combining local light-induced heat sources with sensitive nanoscale thermometry, it may also be possible to engineer biological processes at the subcellular level. Here we demonstrate a new approach to nanoscale thermometry that uses coherent manipulation of the electronic spin associated with nitrogen-vacancy colour centres in diamond. Our technique makes it possible to detect temperature variations as small as 1.8 mK (a sensitivity of 9 mK Hz(-1/2)) in an ultrapure bulk diamond sample. Using nitrogen-vacancy centres in diamond nanocrystals (nanodiamonds), we directly measure the local thermal environment on length scales as short as 200 nanometres. Finally, by introducing both nanodiamonds and gold nanoparticles into a single human embryonic fibroblast, we demonstrate temperature-gradient control and mapping at the subcellular level, enabling unique potential applications in life sciences.
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              Highly efficient and stable InP/ZnSe/ZnS quantum dot light-emitting diodes

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                Author and article information

                Journal
                JACS Au
                JACS Au
                au
                jaaucr
                JACS Au
                American Chemical Society
                2691-3704
                11 May 2021
                28 June 2021
                : 1
                : 6
                : 843-851
                Affiliations
                []Department of Chemistry, Université de Sherbrooke , Sherbrooke, Québec J1K 2R1, Canada
                []Institute of Materials Research and Engineering (A*STAR) , 2 Fusionopolis Way, Innovis, #08-03, Singapore 138634
                [§ ]Department of Chemistry and Biochemistry, University of Windsor , Windsor, Ontario N9B 3P4, Canada
                Author notes
                Author information
                http://orcid.org/0000-0001-5999-0414
                http://orcid.org/0000-0001-5589-2905
                http://orcid.org/0000-0001-7363-1186
                Article
                10.1021/jacsau.1c00055
                8395659
                34467337
                961ef9a0-c138-4129-b601-e1874783b5f8
                © 2021 The Authors. Published by American Chemical Society

                Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works ( https://creativecommons.org/licenses/by-nc-nd/4.0/).

                History
                : 09 February 2021
                Funding
                Funded by: Natural Sciences and Engineering Research Council of Canada, doi 10.13039/501100000038;
                Award ID: NA
                Funded by: Canada Research Chairs, doi 10.13039/501100001804;
                Award ID: NA
                Funded by: Agency for Science, Technology and Research, doi 10.13039/501100001348;
                Award ID: NA
                Funded by: Canada Foundation for Innovation, doi 10.13039/501100000196;
                Award ID: NA
                Categories
                Article
                Custom metadata
                au1c00055
                au1c00055

                graphitic carbon dot,fluorophore,blinking,photobleaching,photophysics,microscopy

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