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      Effect of Electric Current on Beads Formation in Electrospinning of Poly(Vinyl Alcohol)

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          Abstract

          We investigate effects of electric current on formations of beads in electrospinning by changing an electric conductivity of a poly(vinyl alcohol) (PVA) aqueous solution and spinning conditions, such as applied voltage, distance between a tip of needle and a collector, and relative humidity. From the results of experiments done by changing the conductivity of PVA aqueous solution and spinning conditions, we found that a beads formation is suppressed at a lower electric current. Furthermore, when the electrospinnings are performed at a certain constant electric current in various spinning conditions where the applied voltage and tip-collector distance are changed so as to give the same constant electric current, resultant PVA fibers have no beads and almost the same distribution of fiber diameter.

          Most cited references25

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          Bending instability of electrically charged liquid jets of polymer solutions in electrospinning

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            Electrospinning of chitosan dissolved in concentrated acetic acid solution.

            Chitosan nanofibers were electrospun from aqueous chitosan solution using concentrated acetic acid solution as a solvent. A uniform nanofibrous mat of average fiber diameter of 130 nm was obtained from the following optimum condition: 7% chitosan solution in aqueous 90% acetic acid solution was successfully electrospun in the electric field of 4 kV/cm. The aqueous acetic acid concentration higher than 30% was prerequisite for chitosan nanofiber formation, because more concentrated acetic acid in water progressively decreased surface tension of the chitosan solution and concomitantly increased charge density of jet without significant effect on solution viscosity. However, acetic acid solution more than 90% did not dissolve enough chitosan to make spinnable viscous concentration. Only chitosan of a molecular weight of 106,000 g/mol produced bead-free chitosan nanofibers, while low- or high-molecular-weight chitosans of 30,000 and 398,000 g/mol did not. Average fiber diameters and size distribution decreased with increasing electric field and more bead defects appeared at 5 kV/cm or more.
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              Electrospinning of polyurethane fibers

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                Author and article information

                Journal
                ipp
                International Polymer Processing
                Carl Hanser Verlag
                0930-777X
                2195-8602
                2008
                : 23
                : 4
                : 377-384
                Affiliations
                1 Department of Polymer Science and Engineering, Yamagata University, Yonezawa, Japan
                2 Central Research Laboratory, Japan Vilene Company Limited, Ibaraki, Japan
                3 Japan Science and Technology Agency, CREST
                Author notes
                Mail address: Kiyohito Koyama, Department of Polymer Science and Engineering, Yamagata University, 4-3-16 Jyonann, Yonezawa 992-8510, Japan. E-mail: koyama@ 123456yamagata-u.ac.jp
                Article
                IPP2140
                10.3139/217.2140
                a196180d-f06d-4c7c-89ca-7f902cf84c23
                © 2008, Carl Hanser Verlag, Munich
                History
                : 17 September 2007
                : 21 May 2008
                Page count
                References: 30, Pages: 8
                Categories
                Regular Contributed Articles

                Polymer science,Materials technology,Materials characterization,General engineering,Polymer chemistry

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