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      Periodic mesoporous organosilicas for advanced applications

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      NPG Asia Materials

      Springer Nature

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          Silica-based mesoporous organic-inorganic hybrid materials.

          Mesoporous organic-inorganic hybrid materials, a new class of materials characterized by large specific surface areas and pore sizes between 2 and 15 nm, have been obtained through the coupling of inorganic and organic components by template synthesis. The incorporation of functionalities can be achieved in three ways: by subsequent attachment of organic components onto a pure silica matrix (grafting), by simultaneous reaction of condensable inorganic silica species and silylated organic compounds (co-condensation, one-pot synthesis), and by the use of bissilylated organic precursors that lead to periodic mesoporous organosilicas (PMOs). This Review gives an overview of the preparation, properties, and potential applications of these materials in the areas of catalysis, sorption, chromatography, and the construction of systems for controlled release of active compounds, as well as molecular switches, with the main focus being on PMOs.
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            Novel Mesoporous Materials with a Uniform Distribution of Organic Groups and Inorganic Oxide in Their Frameworks

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              Low dielectric constant materials for microelectronics

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                Author and article information

                Journal
                NPG Asia Materials
                NPG Asia Mater
                Springer Nature
                1884-4049
                1884-4057
                April 2014
                April 25 2014
                April 2014
                : 6
                : 4
                : e96
                Article
                10.1038/am.2014.13
                © 2014

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