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      Continuous Time Random Walk with time-dependent jump probability : A Direct Probabilistic Approach

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          Abstract

          We investigate the dynamics of a particle executing a general Continuous Time Random Walk (CTRW) in three dimensions under the influence of arbitrary time-varying external fields. Contrary to the general approach in recent works, our method invokes neither the Fractional Fokker-Planck equation (FFPE) nor the Stochastic Langevin Equation (SLE). Rather, we use rigorous probability arguments to derive the general expression for moments of all orders of the position probability density of the random walker for arbitrary waiting time density and jump probability density. Closed form expression for the position probability density is derived for the memoryless condition. For the special case of CTRW on a one-dimensional lattice with nearest neighbour jumps, our equations confirm the phenomena of "death of linear response" and "field-induced dispersion" for sub-diffusion pointed out in [I. M. Sokolov and J. Klafter, Phys. Rev. Lett. {\bf 97}, 140602 (2006)]. However, our analysis produces additional terms in the expressions for higher moments, which have non-trivial consequences. We show that the disappearance of these terms result from the approximation involved in taking the continuum limit to derive the generalized Fokker-Planck equation. This establishes the incompleteness of the FFPE formulation, especially in predicting the higher moments. We also discuss how different predictions of the model alter if we allow jumps beyond nearest neighbours and possible circumstances where this becomes relevant.

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          Fractional Fokker-Planck equation, solution, and application

          E. Barkai (2001)
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            Exact Solution for the Influence of Spectral Diffusion on Single-Molecule Photon-Statistics

            We investigate the distribution of number of photons emitted by a single molecule undergoing a spectral diffusion process and interacting with a continuous wave field. Using a generating function formalism an exact analytical formula for Mandel's \(Q\) parameter is obtained. The solution exhibits transitions between: (i) Quantum sub-Poissonian and Classical super-Poissonian behaviors, and (ii) fast to slow modulation limits. Our solution yields the conditions on the magnitude of the spectral diffusion time scales on which these transitions are observed. We show how to choose the Rabi frequency in such a way that the Quantum sub-Poissonian nature of the emission process becomes strongest, we find \({\Omega^2 \over \Gamma} = {\Gamma_{{\rm SD}} + \Gamma \over 2}\) where \(\Gamma_{{\rm SD}}\) (\(\Gamma\)) is the spectral diffusion (radiative) contribution to the width of the line shape.
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              Author and article information

              Journal
              13 December 2011
              Article
              1112.3253
              aa1a99d9-c6b6-48ef-bbed-59bd5114873b

              http://arxiv.org/licenses/nonexclusive-distrib/1.0/

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              Custom metadata
              26 pages, 2 figures
              cond-mat.stat-mech

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