Superconducting electron systems of solids hosting flat bands are studied, with a view to improved understanding of the fundamental physics giving rise to high-temperature superconductivity. We present a modified form of the set of Gor'kov equations of BCS theory that incorporates a Mott-like gap in the single-particle spectrum. Such a quantity is emergent in systems with flat bands having interactions repulsive in the Cooper channel, provided particle-hole symmetry is broken. The equations so obtained are applied to the elucidation of features of the two-gap structure of single-particle spectra of underdoped high-\(T_c\) superconductors, as revealed in angle-resolved photoemission spectrometry.