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      Direct observation of a ferri-to-ferromagnetic transition in a fluoride-bridged 3d–4f molecular cluster

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          Efficient iterative schemes forab initiototal-energy calculations using a plane-wave basis set

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            Lanthanide double-decker complexes functioning as magnets at the single-molecular level.

            Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property. The temperature ranges in which the behavior was observed were far higher than that of the transition-metal-cluster single-molecule magnets (SMMs). The significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs. The effective energy barrier for reversal of the magnetic moment is determined by the ligand field around a lanthanide ion, which gives the lowest degenerate substate a large |Jz| value and large energy separations from the rest of the substates in the ground-state multiplets.
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              Strategies towards single molecule magnets based on lanthanide ions

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                Author and article information

                Journal
                CSHCBM
                Chem. Sci.
                Chem. Sci.
                Royal Society of Chemistry (RSC)
                2041-6520
                2041-6539
                2012
                2012
                : 3
                : 4
                : 1024-1032
                Article
                10.1039/C2SC00794K
                aab9baad-daeb-49f2-93df-e92f682265c7
                © 2012
                History

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