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      Equivalent Porous Media (EPM) Simulation of Groundwater Hydraulics and Contaminant Transport in Karst Aquifers

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          Abstract

          Karst aquifers have a high degree of heterogeneity and anisotropy in their geologic and hydrogeologic properties which makes predicting their behavior difficult. This paper evaluates the application of the Equivalent Porous Media (EPM) approach to simulate groundwater hydraulics and contaminant transport in karst aquifers using an example from the North Coast limestone aquifer system in Puerto Rico. The goal is to evaluate if the EPM approach, which approximates the karst features with a conceptualized, equivalent continuous medium, is feasible for an actual project, based on available data and the study scale and purpose. Existing National Oceanic Atmospheric Administration (NOAA) data and previous hydrogeological U. S. Geological Survey (USGS) studies were used to define the model input parameters. Hydraulic conductivity and specific yield were estimated using measured groundwater heads over the study area and further calibrated against continuous water level data of three USGS observation wells. The water-table fluctuation results indicate that the model can practically reflect the steady-state groundwater hydraulics (normalized RMSE of 12.4%) and long-term variability (normalized RMSE of 3.0%) at regional and intermediate scales and can be applied to predict future water table behavior under different hydrogeological conditions. The application of the EPM approach to simulate transport is limited because it does not directly consider possible irregular conduit flow pathways. However, the results from the present study suggest that the EPM approach is capable to reproduce the spreading of a TCE plume at intermediate scales with sufficient accuracy (normalized RMSE of 8.45%) for groundwater resources management and the planning of contamination mitigation strategies.

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          Review: Groundwater flow and transport modeling of karst aquifers, with particular reference to the North Coast Limestone aquifer system of Puerto Rico

          Karst systems have a high degree of heterogeneity and anisotropy, which makes them behave very differently from other aquifers. Slow seepage through the rock matrix and fast flow through conduits and fractures result in a high variation in spring response to precipitation events. Contaminant storage occurs in the rock matrix and epikarst, but contaminant transport occurs mostly along preferential pathways that are typically inaccessible locations, which makes modeling of karst systems challenging. Computer models for understanding and predicting hydraulics and contaminant transport in aquifers make assumptions about the distribution and hydraulic properties of geologic features that may not always apply to karst aquifers. This paper reviews the basic concepts, mathematical descriptions, and modeling approaches for karst systems. The North Coast Limestone aquifer system of Puerto Rico (USA) is introduced as a case study to illustrate and discuss the application of groundwater models in karst aquifer systems to evaluate aquifer contamination.
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            Spatiotemporal changes of CVOC concentrations in karst aquifers: analysis of three decades of data from Puerto Rico.

            We studied the spatial and temporal distribution patterns of Chlorinated Volatile Organic Compounds (CVOCs) in the karst aquifers in northern Puerto Rico (1982-2013). Seventeen CVOCs were widely detected across the study area, with the most detected and persistent contaminated CVOCs including trichloroethylene (TCE), tetrachloroethylene (PCE), carbon tetrachloride (CT), chloroform (TCM), and methylene chloride (DCM). Historically, 471 (76%) and 319 (52%) of the 615 sampling sites have CVOC concentrations above the detection limit and maximum contamination level (MCL), respectively. The spatiotemporal patterns of the CVOC concentrations showed two clusters of contaminated areas, one near the Superfund site "Upjohn" and another near "Vega Alta Public Supply Wells." Despite a decreasing trend in concentrations, there is a general northward movement and spreading of contaminants even beyond the extent of known sources of the Superfund and landfill sites. Our analyses suggest that, besides the source conditions, karst characteristics (high heterogeneity, complex hydraulic and biochemical environment) are linked to the long-term spatiotemporal patterns of CVOCs in groundwater.
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              Validation of a numerical indicator of microbial contamination for karst springs.

              Rapid changes in spring water quality in karst areas due to rapid recharge of bacterially contaminated water are a major concern for drinking water suppliers and users. The main objective of this study was to use field experiments with fecal indicators to verify the vulnerability of a karst spring to pathogens, as determined by using a numerical modeling approach. The groundwater modeling was based on linear storage models that can be used to simulate karst water flow. The vulnerability of the karst groundwater is estimated using such models to calculate criteria that influence the likelihood of spring water being affected by microbial contamination. Specifically, the temporal variation in the vulnerability, depending on rainfall events and overall recharge conditions, can be assessed and quantified using the dynamic vulnerability index (DVI). DVI corresponds to the ratio of conduit to diffuse flow contributions to spring discharge. To evaluate model performance with respect to predicted vulnerability, samples from a spring were analyzed for Escherichia coli, enterococci, Clostridium perfringens, and heterotrophic plate count bacteria during and after several rainfall events. DVI was shown to be an indication of the risk of fecal contamination of spring water with sufficient accuracy to be used in drinking water management. We conclude that numerical models are a useful tool for evaluating the vulnerability of karst systems to pathogens under varying recharge conditions. Copyright © 2010 The Author(s). Journal compilation © 2010 National Ground Water Association.
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                Author and article information

                Contributors
                Role: Editor
                Journal
                PLoS One
                PLoS ONE
                plos
                plosone
                PLoS ONE
                Public Library of Science (San Francisco, CA USA )
                1932-6203
                30 September 2015
                2015
                : 10
                : 9
                : e0138954
                Affiliations
                [1 ]Department of Civil and Environmental Engineering, Northeastern University, Boston, Massachusetts 02115, United States of America
                [2 ]Department of Engineering Geology, Institute of Applied Geosciences, Karlsruhe Institute of Technology, 76131, Karlsruhe, Germany
                [3 ]Department of Civil Engineering and Surveying, University of Puerto Rico, Mayaguez, Puerto Rico 00682, United States of America
                Tsinghua University, CHINA
                Author notes

                Competing Interests: The authors have declared that no competing interests exist.

                Conceived and designed the experiments: RG XY CB FLH IYP ANA. Performed the experiments: RG. Analyzed the data: RG XY CB FLH. Contributed reagents/materials/analysis tools: RG XY CB FLH IYP ANA. Wrote the paper: RG XY CB FLH. Initiated this work: IYP ANA.

                Article
                PONE-D-15-22712
                10.1371/journal.pone.0138954
                4589392
                26422202
                aec602c7-5f4f-469c-9db8-aa766d151a2f
                Copyright @ 2015

                This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited

                History
                : 26 May 2015
                : 5 September 2015
                Page count
                Figures: 13, Tables: 0, Pages: 21
                Funding
                Support of the work described is provided through award number P42ES017198 from the National Institute of Environmental Health Sciences ( www.niehs.nih.gov) to the PROTECT research project (ANA). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.
                Categories
                Research Article
                Custom metadata
                The relevant hydrogeological and environmental data underlying the findings are all included in the figures within the paper.

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