For Publishers
DiscoveryMetadataPeer reviewHostingPublishing
For Researchers
JoinPublishReviewCollect
Register
Blog
About
Search
Advanced search
My ScienceOpen
Search
For Publishers
For Researchers
Blog
About
96
views
12
references
 Top references
cited by
127
    
0 reviews
 Review
0
comments
 Comment
0
recommends
+1 Recommend
0 collections
    0
    shares
      345
      similar
       All similar
      • Record: found
      • Abstract: found
      • Article: not found

      Cubic Perovskite Structure of Black Formamidinium Lead Iodide, α-[HC(NH 2) 2]PbI 3, at 298 K

      rapid-communication

      Read this article at

      ScienceOpenPublisherPMC
      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          The structure of black formamidinium lead halide, α-[HC(NH 2) 2]PbI 3, at 298 K has been refined from high resolution neutron powder diffraction data and found to adopt a cubic perovskite unit cell, a = 6.3620(8) Å. The trigonal planar [HC(NH 2) 2] + cations lie in the central mirror plane of the unit cell with the formamidinium cations disordered over 12 possible sites arranged so that the C–H bond is directed into a cube face, whereas the −NH 2 groups hydrogen bond (NH···I = 2.75–3.00 Å) with the iodide atoms of the [PbI 3] − framework. High atomic displacement parameters for the formamidinium cation are consistent with rapid molecular rotations at room temperature as evidenced in ab initio molecular dynamic simulations.

          Related collections

          Most cited references12

          • Record: found
          • Abstract: found
          • Article: found
          Is Open Access

          Simple analytical expression for the peak-frequency shifts of plasmonic resonances for sensing

          Jianji Yang, Harald Giessen, Philippe Lalanne (2015)
          We derive a closed-form expression that accurately predicts the peak frequency-shift and broadening induced by tiny perturbations of plasmonic nanoresonators without critically relying on repeated electrodynamic simulations of the spectral response of nanoresonator for various locations, sizes or shapes of the perturbing objects. The force of the present approach, in comparison with other approaches of the same kind, is that the derivation is supported by a mathematical formalism based on a rigorous normalization of the resonance modes of nanoresonators consisting of lossy and dispersive materials. Accordingly, accurate predictions are obtained for a large range of nanoparticle shapes and sizes, used in various plasmonic nanosensors, even beyond the quasistatic limit. The expression gives quantitative insight, and combined with an open-source code, provides accurate and fast predictions that are ideally suited for preliminary designs or for interpretation of experimental data. It is also valid for photonic resonators with large mode volumes.
          Article 0 comments Cited 366 times – based on 0 reviews
          Preprint
               Review now
            Bookmark
            • Record: found
            • Abstract: found
            • Article: not found

            High-efficiency perovskite solar cells based on the black polymorph of HC(NH2)2 PbI3.

            Jin-Wook Lee, Dong-Jin Seol, An-Na Cho … (2014)
            Perovskite solar cells with power conversion efficiencies exceeding 16% at AM 1.5 G one sun illumination are developed using the black polymorph of formamidnium lead iodide, HC(NH2)2 PbI3 . Compared with CH3 NH3 PbI3 , HC(NH2 )2 PbI3 extends its absoprtion to 840 nm and shows no phase transition between 296 and 423 K. Moreover, a solar cell based on HC(NH2 )2 PbI3 exhibits photostability and little I-V hysteresis.
            Article 0 comments Cited 298 times – based on 0 reviews     Review now
              Bookmark
              • Record: found
              • Abstract: found
              • Article: found
              Is Open Access

              Probing quantum confinement within single core-multishell nanowires

              Gema Martínez-Criado, Alejandro Homs, Benito Alén … (2013)
              Theoretically core-multishell nanowires under a cross-section of hexagonal geometry should exhibit peculiar confinement effects. Using a hard X-ray nanobeam, here we show experimental evidence for carrier localization phenomena at the hexagon corners by combining synchrotron excited optical luminescence with simultaneous X-ray fluorescence spectroscopy. Applied to single coaxial n-GaN/InGaN multiquantum-well/p-GaN nanowires, our experiment narrows the gap between optical microscopy and high-resolution X-ray imaging, and calls for further studies on the underlying mechanisms of optoelectronic nanodevices.
              Article 0 comments Cited 297 times – based on 0 reviews
              Preprint
                   Review now
                Bookmark
                All references

                Author and article information

                Journal
                Journal ID (nlm-ta): J Phys Chem Lett
                Journal ID (iso-abbrev): J Phys Chem Lett
                Journal ID (publisher-id): jz
                Journal ID (coden): jpclcd
                Title: The Journal of Physical Chemistry Letters
                Publisher: American Chemical Society
                ISSN (Electronic): 1948-7185
                Publication date (Electronic): 04 August 2015
                Publication date (Print): 20 August 2015
                Volume: 6
                Issue: 16
                Pages: 3209-3212
                Affiliations
                [1]Centre for Sustainable Chemical Technologies and Department of Chemistry, University of Bath , Bath, BA2 7AY, United Kingdom
                Author notes
                Article
                DOI: 10.1021/acs.jpclett.5b01432
                PMC ID: 4603719
                SO-VID: afc4e31d-953e-4659-b655-0521cc6fc5ed
                Copyright © Copyright © 2015 American Chemical Society
                License:

                This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.

                History
                Date received : 07 July 2015
                Date accepted : 04 August 2015
                Categories
                Subject: Letter
                Custom metadata
                document-id-old-9 jz5b01432
                document-id-new-14 jz-2015-01432t
                ccc-price

                ScienceOpen disciplines: Physical chemistry
                Data availability:
                ScienceOpen disciplines: Physical chemistry

                Comments

                Comment on this article

                scite_

                Similar content345

                See all similar

                Cited by127

                See all cited by

                Most referenced authors1,712

                See all reference authors