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      Supercritical Water Gasification of Guaiacol with Acetic Acid as a Radical Scavenger: Interaction Effect on Char Formation and Gas Composition

      research-article
      Author(s): † , ‡ , ‡ ,
      Publication date (Electronic):
      Journal: ACS Omega
      Publisher: American Chemical Society

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          Abstract

          Supercritical water gasification (SCWG) of mixtures of guaiacol and acetic acid was carried out in a continuous reactor at 600 °C and 25 MPa with a residence time of 94 s. Different concentrations of acetic acid were employed to investigate the effect of acetic acid on product yield and gas composition. The interaction between guaiacol and acetic acid during SCWG was discussed. Acetic acid, as a radical scavenger, was found to inhibit radical polymerization, resulting in the suppression of char formation.

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          Biomass gasification in near- and super-critical water: Status and prospects

          S. Kersten, A. Kruse, T Minowa … (2005)
          Article 0 comments Cited 64 times – based on 0 reviews     Review now
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            Biomass Conversion in Water at 330−410 °C and 30−50 MPa. Identification of Key Compounds for Indicating Different Chemical Reaction Pathways

            A Gawlik, A. Kruse (2003)
            Article 0 comments Cited 50 times – based on 0 reviews     Review now
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              Char Formation Mechanism in Supercritical Water Gasification Process: A Study of Model Compounds

              Athika Chuntanapum, Yukihiko Matsumura (2010)
              Article 0 comments Cited 21 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Journal ID (nlm-ta): ACS Omega
                Journal ID (publisher-id): ao
                Journal ID (coden): acsodf
                Title: ACS Omega
                Publisher: American Chemical Society
                ISSN (Electronic): 2470-1343
                Publication date (Electronic): 18 September 2020
                Publication date Collection: 29 September 2020
                Volume: 5
                Issue: 38
                Pages: 24818-24825
                Affiliations
                [† ]Department of Mechanical Science and Engineering, Hiroshima University , Higashi-Hiroshima 739-8527, Japan
                [‡ ]Mechanical Engineering Program, Graduate School of Advanced Science and Engineering, Hiroshima University , 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Japan
                Author notes
                [* ]Email: mat@ 123456hiroshima-u.ac.jp . Tel: +81-82-424-7561.
                Article
                DOI: 10.1021/acsomega.0c03506
                PMC ID: 7528299
                SO-VID: b077738e-f644-4b73-a377-e80ad4e95947
                Copyright ©
                License:

                This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.

                History
                Date received : 22 July 2020
                Date accepted : 04 September 2020
                Categories
                Subject: Article
                Custom metadata
                document-id-old-9 ao0c03506
                document-id-new-14 ao0c03506
                ccc-price

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