Blog
About

2
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: not found
      • Article: not found

      Defective Metal-Organic Frameworks

      Read this article at

      ScienceOpenPublisher
      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Related collections

          Most cited references 153

          • Record: found
          • Abstract: found
          • Article: not found

          Functional Porous Coordination Polymers

            Bookmark
            • Record: found
            • Abstract: found
            • Article: not found

            Reticular synthesis and the design of new materials.

            The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
              Bookmark
              • Record: found
              • Abstract: found
              • Article: not found

              Soft porous crystals.

              The field of host-guest complexation is intensely attractive from diverse perspectives, including materials science, chemistry and biology. The uptake and encapsulation of guest species by host frameworks are being investigated for a wide variety of purposes, including separation and storage using zeolites, and recognition and sensing by enzymes in solution. Here we focus on the concept of the cooperative integration of 'softness' and 'regularity'. Recent developments on porous coordination polymers (or metal-organic frameworks) have provided the inherent properties that combine these features. Such soft porous crystals exhibit dynamic frameworks that are able to respond to external stimuli such as light, electric fields or the presence of particular species, but they are also crystalline and can change their channels reversibly while retaining high regularity. We discuss the relationship between the structures and properties of these materials in view of their practical applications.
                Bookmark

                Author and article information

                Affiliations
                [1 ]Chair of Inorganic and Metal-Organic Chemistry; Department of Chemistry; Technical University of Munich; Lichtenbergstraße 4 85748 Garching Germany
                Journal
                Advanced Materials
                Adv. Mater.
                Wiley
                09359648
                September 2018
                September 2018
                January 24 2018
                : 30
                : 37
                : 1704501
                10.1002/adma.201704501
                © 2018

                http://doi.wiley.com/10.1002/tdm_license_1.1

                http://onlinelibrary.wiley.com/termsAndConditions#vor

                Comments

                Comment on this article