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      Recent Advances in Metal-Catalyzed Alkyl–Boron (C(sp3)–C(sp2)) Suzuki-Miyaura Cross-Couplings

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      Catalysts
      MDPI AG

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          Abstract

          Boron chemistry has evolved to become one of the most diverse and applied fields in organic synthesis and catalysis. Various valuable reactions such as hydroborylations and Suzuki–Miyaura cross-couplings (SMCs) are now considered as indispensable methods in the synthetic toolbox of researchers in academia and industry. The development of novel sterically- and electronically-demanding C(sp3)–Boron reagents and their subsequent metal-catalyzed cross-couplings attracts strong attention and serves in turn to expedite the wheel of innovative applications of otherwise challenging organic adducts in different fields. This review describes the significant progress in the utilization of classical and novel C(sp3)–B reagents (9-BBN and 9-MeO-9-BBN, trifluoroboronates, alkylboranes, alkylboronic acids, MIDA, etc.) as coupling partners in challenging metal-catalyzed C(sp3)–C(sp2) cross-coupling reactions, such as B-alkyl SMCs after 2001.

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          Palladium-catalyzed inter- and intramolecular cross-coupling reactions of B-alkyl-9-borabicyclo[3.3.1]nonane derivatives with 1-halo-1-alkenes or haloarenes. Syntheses of functionalized alkenes, arenes, and cycloalkenes via a hydroboration-coupling sequence

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            Addressing the Challenges in Suzuki–Miyaura Cross-Couplings by Ligand Design

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              Boron Chemistry: An Overview

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                Author and article information

                Contributors
                Journal
                CATACJ
                Catalysts
                Catalysts
                MDPI AG
                2073-4344
                March 2020
                March 05 2020
                : 10
                : 3
                : 296
                Article
                10.3390/catal10030296
                b6aa4b19-2e76-488e-8b37-7f00ff535e66
                © 2020

                https://creativecommons.org/licenses/by/4.0/

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