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      Insensitivity to Flaws Leads to Damage Tolerance in Brittle Architected Meta-Materials

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          Abstract

          Cellular solids are instrumental in creating lightweight, strong, and damage-tolerant engineering materials. By extending feature size down to the nanoscale, we simultaneously exploit the architecture and material size effects to substantially enhance structural integrity of architected meta-materials. We discovered that hollow-tube alumina nanolattices with 3D kagome geometry that contained pre-fabricated flaws always failed at the same load as the pristine specimens when the ratio of notch length (a) to sample width (w) is no greater than 1/3, with no correlation between failure occurring at or away from the notch. Samples with (a/w) > 0.3, and notch length-to-unit cell size ratios of (a/l) > 5.2, failed at a lower peak loads because of the higher sample compliance when fewer unit cells span the intact region. Finite element simulations show that the failure is governed by purely tensile loading for (a/w) < 0.3 for the same (a/l); bending begins to play a significant role in failure as (a/w) increases. This experimental and computational work demonstrates that the discrete-continuum duality of architected structural meta-materials may give rise to their damage tolerance and insensitivity of failure to the presence of flaws even when made entirely of intrinsically brittle materials.

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          Strong, lightweight, and recoverable three-dimensional ceramic nanolattices.

          Ceramics have some of the highest strength- and stiffness-to-weight ratios of any material but are suboptimal for use as structural materials because of their brittleness and sensitivity to flaws. We demonstrate the creation of structural metamaterials composed of nanoscale ceramics that are simultaneously ultralight, strong, and energy-absorbing and can recover their original shape after compressions in excess of 50% strain. Hollow-tube alumina nanolattices were fabricated using two-photon lithography, atomic layer deposition, and oxygen plasma etching. Structures were made with wall thicknesses of 5 to 60 nanometers and densities of 6.3 to 258 kilograms per cubic meter. Compression experiments revealed that optimizing the wall thickness-to-radius ratio of the tubes can suppress brittle fracture in the constituent solid in favor of elastic shell buckling, resulting in ductile-like deformation and recoverability.
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            Fabrication and deformation of three-dimensional hollow ceramic nanostructures.

            Creating lightweight, mechanically robust materials has long been an engineering pursuit. Many siliceous skeleton species--such as diatoms, sea sponges and radiolarians--have remarkably high strengths when compared with man-made materials of the same composition, yet are able to remain lightweight and porous. It has been suggested that these properties arise from the hierarchical arrangement of different structural elements at their relevant length scales. Here, we report the fabrication of hollow ceramic scaffolds that mimic the length scales and hierarchy of biological materials. The constituent solids attain tensile strengths of 1.75 GPa without failure even after multiple deformation cycles, as revealed by in situ nanomechanical experiments and finite-element analysis. We discuss the high strength and lack of failure in terms of stress concentrators at surface imperfections and of local stresses within the microstructural landscape. Our findings suggest that the hierarchical design principles offered by hard biological organisms can be applied to create damage-tolerant lightweight engineering materials.
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              Mechanisms of failure in nanoscale metallic glass.

              The emergence of size-dependent mechanical strength in nanosized materials is now well-established, but no fundamental understanding of fracture toughness or flaw sensitivity in nanostructures exists. We report the fabrication and in situ fracture testing of ∼70 nm diameter Ni-P metallic glass samples with a structural flaw. Failure occurs at the structural flaw in all cases, and the failure strength of flawed samples was reduced by 40% compared to unflawed samples. We explore deformation and failure mechanisms in a similar nanometallic glass via molecular dynamics simulations, which corroborate sensitivity to flaws and reveal that the structural flaw shifts the failure mechanism from shear banding to cavitation. We find that failure strength and deformation in amorphous nanosolids depend critically on the presence of flaws.
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                Author and article information

                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group
                2045-2322
                03 February 2016
                2016
                : 6
                : 20570
                Affiliations
                [1 ]California Institute of Technology , Pasadena, CA, USA
                [2 ]Institute of High Performance Computing, (A*STAR), 1 Fusionopolis Way, #16-16 Connexis , Singapore 138632
                Author notes
                Article
                srep20570
                10.1038/srep20570
                4738344
                26837581
                b8b2a4c3-0969-440e-8b05-7123aca3d13d
                Copyright © 2016, Macmillan Publishers Limited

                This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

                History
                : 04 September 2015
                : 06 January 2016
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