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      Recent advances in the application of Diels–Alder reactions involving o-quinodimethanes, aza- o-quinone methides and o-quinone methides in natural product total synthesis

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          Abstract

          This review summarizes recent advances in Diels–Alder reactions involving o-QDMs, o-QMs and aza- o-QMs. The power and potential of this strategy in organic synthesis and natural product total synthesis is highlighted.

          Abstract

          In recent decades, transient and highly reactive ortho-quinodimethanes ( o-QDMs), ortho-quinone methides ( o-QMs) and aza- ortho-quinone methides (aza- o-QMs) have attracted much attention and have been extensively studied and applied in organic synthesis, especially natural product total synthesis. This review summarizes recent advances in Diels–Alder reactions involving in situ-generated o-QDMs, o-QMs and aza- o-QMs, highlighting the power and potential of this strategy in organic synthesis and natural product total synthesis. An overview of the methods for generating these intermediates is also available.

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          Stronger Brønsted acids.

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            Complete field guide to asymmetric BINOL-phosphate derived Brønsted acid and metal catalysis: history and classification by mode of activation; Brønsted acidity, hydrogen bonding, ion pairing, and metal phosphates.

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                Author and article information

                Contributors
                Journal
                CSRVBR
                Chemical Society Reviews
                Chem. Soc. Rev.
                Royal Society of Chemistry (RSC)
                0306-0012
                1460-4744
                October 29 2018
                2018
                : 47
                : 21
                : 7926-7953
                Affiliations
                [1 ]Shanghai Key Laboratory of Green Chemistry and Chemical Processes
                [2 ]School of Chemistry and Molecular Engineering
                [3 ]East China Normal University
                [4 ]Shanghai 200062
                [5 ]China
                Article
                10.1039/C8CS00274F
                29993045
                b9eb9def-9405-4d48-b5a0-9cbd7d57eb3d
                © 2018

                http://rsc.li/journals-terms-of-use

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