Preparing epoxidized vegetable oil from waste generated by the kapok fiber industry and assessing its thermal stabilization effect as a co-stabilizer for polyvinyl chloride

Abstract

This paper describes the epoxidation of vegetable oil derived from waste kapok seeds using performic acid, which was generated in situ with sulfuric acid acting as a catalyst. The mole ratio of formic acid to double bonds varied between 0.25 and 1.00. The completion of the reaction has been verified by analyzing FTIR and NMR spectra. The resulting epoxidized kapok seed oil (EKSO) has a maximum oxirane oxygen content of 2.7%, achieved at a formic acid to double bond mole ratio of 0.5. The study has also examined the potential use of EKSO as a co-stabilizer in the presence of Ca/Zn stearate for stabilizing polyvinyl chloride (PVC). Both static and dynamic tests demonstrated that incorporating EKSO into the Ca/Zn stearate system leads to a significant increase in the thermal stability of PVC. Moreover, the effectiveness of EKSO as a co-stabilizer was found to be comparable to that of epoxidized soybean oil (ESBO). However, the use of EKSO did result in a decrease in the strength of PVC due to an increase in plasticity, although this effect was minimal at low dosages and was also observed with ESBO. On the other hand, when utilizing small doses (<2 phr), there is a tendency for flowability to decrease, but the reduction is not significant either. Overall, these findings suggest that EKSO could be a valuable co-stabilizer for PVC in industrial applications, as it enhances PVC's thermal stability without significantly compromising its mechanical and flow properties.

Highlights

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  Waste kapok seeds yield successful epoxidized vegetable oil (EKSO).

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  EKSO contains up to 2.7% oxirane oxygen, at maximum.

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  Adding EKSO to Ca/Zn stearate improves PVC's thermal stability.

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  EKSO is comparable to epoxidized soybean oil as a co-stabilizer.

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  EKSO shows potential as a valuable co-stabilizer for industrial PVC applications.