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      Opportunities for Bio-Based Solvents Created as Petrochemical and Fuel Products Transition towards Renewable Resources

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          Abstract

          The global bio-based chemical market is growing in size and importance. Bio-based solvents such as glycerol and 2-methyltetrahydrofuran are often discussed as important introductions to the conventional repertoire of solvents. However adoption of new innovations by industry is typically slow. Therefore it might be anticipated that neoteric solvent systems (e.g., ionic liquids) will remain niche, while renewable routes to historically established solvents will continue to grow in importance. This review discusses bio-based solvents from the perspective of their production, identifying suitable feedstocks, platform molecules, and relevant product streams for the sustainable manufacturing of conventional solvents.

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          Most cited references346

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          Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited

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            Room-temperature ionic liquids: solvents for synthesis and catalysis. 2.

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              Conversion of biomass to selected chemical products.

              This critical review provides a survey illustrated by recent references of different strategies to achieve a sustainable conversion of biomass to bioproducts. Because of the huge number of chemical products that can be potentially manufactured, a selection of starting materials and targeted chemicals has been done. Also, thermochemical conversion processes such as biomass pyrolysis or gasification as well as the synthesis of biofuels were not considered. The synthesis of chemicals by conversion of platform molecules obtained by depolymerisation and fermentation of biopolymers is presently the most widely envisioned approach. Successful catalytic conversion of these building blocks into intermediates, specialties and fine chemicals will be examined. However, the platform molecule value chain is in competition with well-optimised, cost-effective synthesis routes from fossil resources to produce chemicals that have already a market. The literature covering alternative value chains whereby biopolymers are converted in one or few steps to functional materials will be analysed. This approach which does not require the use of isolated, pure chemicals is well adapted to produce high tonnage products, such as paper additives, paints, resins, foams, surfactants, lubricants, and plasticisers. Another objective of the review was to examine critically the green character of conversion processes because using renewables as raw materials does not exempt from abiding by green chemistry principles (368 references).
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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Int J Mol Sci
                Int J Mol Sci
                ijms
                International Journal of Molecular Sciences
                MDPI
                1422-0067
                28 July 2015
                August 2015
                : 16
                : 8
                : 17101-17159
                Affiliations
                Green Chemistry Centre of Excellence, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK; E-Mails: thomas.farmer@ 123456york.ac.uk (T.J.F.); andrew.hunt@ 123456york.ac.uk (A.J.H.); james.sherwood@ 123456york.ac.uk (J.S.)
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: james.clark@ 123456york.ac.uk ; Tel.: +44-(0)-1904-322559.
                Article
                ijms-16-17101
                10.3390/ijms160817101
                4581186
                26225963
                bb9404bc-af3d-4e37-bba0-6f2dddcb6040
                © 2015 by the authors; licensee MDPI, Basel, Switzerland.

                This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 22 June 2015
                : 17 July 2015
                Categories
                Review

                Molecular biology
                bio-based solvent,biomass,bio-refinery,green solvent,platform molecules
                Molecular biology
                bio-based solvent, biomass, bio-refinery, green solvent, platform molecules

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