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      Inorganic engineered nanoparticles in drinking water treatment: a critical review

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          Abstract

          This review summarizes the recent research in the field of inorganic engineered nanoparticle development with direct or potential interest for drinking water treatment.

          This review summarizes the recent research in the field of inorganic engineered nanoparticle development with direct or potential interest for drinking water treatment. The incorporation of engineered nanoparticles into drinking water treatment technologies against the removal of heavy metals, microorganisms and organic pollutants appears as a very dynamic branch of nanotechnology. Nanoparticles owe their potential to the high specific surface area and surface reactivity compared to conventional bulk materials. Depending on the mechanism of uptake, nanoparticles can be designed to establish high selectivity against specific pollutants and provide the required efficiency for application. However, despite early encouraging results, nanoparticles meet a number of limitations to get promoted and become part of large-scale water treatment plants. The most important is their availability in the required large quantities and their efficiency to fulfil the strict regulations for drinking water consumption and environmental safety. Both deal with the particle preparation cost and the cost of treatment operation with respect to the increase in supplied water price for the consumers. Under this view, this work attempts to evaluate reported studies according to their possibility to meet the reliable requirements of water technology and also suggests an experimental approach to allow validation of tested nanoparticles.

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          Does the antibacterial activity of silver nanoparticles depend on the shape of the nanoparticle? A study of the Gram-negative bacterium Escherichia coli.

          In this work we investigated the antibacterial properties of differently shaped silver nanoparticles against the gram-negative bacterium Escherichia coli, both in liquid systems and on agar plates. Energy-filtering transmission electron microscopy images revealed considerable changes in the cell membranes upon treatment, resulting in cell death. Truncated triangular silver nanoplates with a {111} lattice plane as the basal plane displayed the strongest biocidal action, compared with spherical and rod-shaped nanoparticles and with Ag(+) (in the form of AgNO(3)). It is proposed that nanoscale size and the presence of a {111} plane combine to promote this biocidal property. To our knowledge, this is the first comparative study on the bactericidal properties of silver nanoparticles of different shapes, and our results demonstrate that silver nanoparticles undergo a shape-dependent interaction with the gram-negative organism E. coli.
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            Nanomedicine in cancer therapy: challenges, opportunities, and clinical applications.

            Cancer is a leading cause of death worldwide. Currently available therapies are inadequate and spur demand for improved technologies. Rapid growth in nanotechnology towards the development of nanomedicine products holds great promise to improve therapeutic strategies against cancer. Nanomedicine products represent an opportunity to achieve sophisticated targeting strategies and multi-functionality. They can improve the pharmacokinetic and pharmacodynamic profiles of conventional therapeutics and may thus optimize the efficacy of existing anti-cancer compounds. In this review, we discuss state-of-the-art nanoparticles and targeted systems that have been investigated in clinical studies. We emphasize the challenges faced in using nanomedicine products and translating them from a preclinical level to the clinical setting. Additionally, we cover aspects of nanocarrier engineering that may open up new opportunities for nanomedicine products in the clinic.
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              Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis.

              Interest in catalysis by metal nanoparticles (NPs) is increasing dramatically, as reflected by the large number of publications in the last five years. This field, "semi-heterogeneous catalysis", is at the frontier between homogeneous and heterogeneous catalysis, and progress has been made in the efficiency and selectivity of reactions and recovery and recyclability of the catalytic materials. Usually NP catalysts are prepared from a metal salt, a reducing agent, and a stabilizer and are supported on an oxide, charcoal, or a zeolite. Besides the polymers and oxides that used to be employed as standard, innovative stabilizers, media, and supports have appeared, such as dendrimers, specific ligands, ionic liquids, surfactants, membranes, carbon nanotubes, and a variety of oxides. Ligand-free procedures have provided remarkable results with extremely low metal loading. The Review presents the recent developments and the use of NP catalysis in organic synthesis, for example, in hydrogenation and C--C coupling reactions, and the heterogeneous oxidation of CO on gold NPs.
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                Author and article information

                Journal
                ESWRAR
                Environmental Science: Water Research & Technology
                Environ. Sci.: Water Res. Technol.
                Royal Society of Chemistry (RSC)
                2053-1400
                2053-1419
                2016
                2016
                : 2
                : 1
                : 43-70
                Article
                10.1039/C5EW00152H
                bc96ea31-4ffc-43db-8003-af7c86f125e0
                © 2016
                History

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