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Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling
Christopher C. Nawrat ,
Christopher R. Jamison ,
Yuriy Slutskyy ,
David W. C. MacMillan ,
Larry E. Overman
September 09 2015
September 09 2015
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Abstract
Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation
under visible light photoredox conditions. Using these precursors, the first net redox-neutral
coupling of tertiary and secondary alcohols with electron-deficient alkenes is achieved.