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      Machine learning applied to single-shot x-ray diagnostics in an XFEL

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          Abstract

          X-ray free-electron lasers (XFELs) are the only sources currently able to produce bright few-fs pulses with tunable photon energies from 100 eV to more than 10 keV. Due to the stochastic SASE operating principles and other technical issues the output pulses are subject to large fluctuations, making it necessary to characterize the x-ray pulses on every shot for data sorting purposes. We present a technique that applies machine learning tools to predict x-ray pulse properties using simple electron beam and x-ray parameters as input. Using this technique at the Linac Coherent Light Source (LCLS), we report mean errors below 0.3 eV for the prediction of the photon energy at 530 eV and below 1.6 fs for the prediction of the delay between two x-ray pulses. We also demonstrate spectral shape prediction with a mean agreement of 97%. This approach could potentially be used at the next generation of high-repetition-rate XFELs to provide accurate knowledge of complex x-ray pulses at the full repetition rate.

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          A tutorial on support vector regression

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            Imaging charge transfer in iodomethane upon x-ray photoabsorption.

            Studies of charge transfer are often hampered by difficulties in determining the charge localization at a given time. Here, we used ultrashort x-ray free-electron laser pulses to image charge rearrangement dynamics within gas-phase iodomethane molecules during dissociation induced by a synchronized near-infrared (NIR) laser pulse. Inner-shell photoionization creates positive charge, which is initially localized on the iodine atom. We map the electron transfer between the methyl and iodine fragments as a function of their interatomic separation set by the NIR-x-ray delay. We observe signatures of electron transfer for distances up to 20 angstroms and show that a realistic estimate of its effective spatial range can be obtained from a classical over-the-barrier model. The presented technique is applicable for spatiotemporal imaging of charge transfer dynamics in a wide range of molecular systems.
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              Fresh-slice multicolour X-ray free-electron lasers

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                Author and article information

                Journal
                2016-10-11
                Article
                1610.03378
                bed1cc8f-97ac-49b2-82eb-b42674382c1c

                http://arxiv.org/licenses/nonexclusive-distrib/1.0/

                History
                Custom metadata
                12 pages, 8 figures
                physics.data-an physics.acc-ph

                High energy & Particle physics,Mathematical & Computational physics
                High energy & Particle physics, Mathematical & Computational physics

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