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      Carbon Dioxide Separation from Flue Gases: A Technological Review Emphasizing Reduction in Greenhouse Gas Emissions

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          Abstract

          Increasing concentrations of greenhouse gases (GHGs) such as CO 2 in the atmosphere is a global warming. Human activities are a major cause of increased CO 2 concentration in atmosphere, as in recent decade, two-third of greenhouse effect was caused by human activities. Carbon capture and storage (CCS) is a major strategy that can be used to reduce GHGs emission. There are three methods for CCS: pre-combustion capture, oxy-fuel process, and post-combustion capture. Among them, post-combustion capture is the most important one because it offers flexibility and it can be easily added to the operational units. Various technologies are used for CO 2 capture, some of them include: absorption, adsorption, cryogenic distillation, and membrane separation. In this paper, various technologies for post-combustion are compared and the best condition for using each technology is identified.

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          Adsorbent materials for carbon dioxide capture from large anthropogenic point sources.

          Since the time of the industrial revolution, the atmospheric CO(2) concentration has risen by nearly 35 % to its current level of 383 ppm. The increased carbon dioxide concentration in the atmosphere has been suggested to be a leading contributor to global climate change. To slow the increase, reductions in anthropogenic CO(2) emissions are necessary. Large emission point sources, such as fossil-fuel-based power generation facilities, are the first targets for these reductions. A benchmark, mature technology for the separation of dilute CO(2) from gas streams is via absorption with aqueous amines. However, the use of solid adsorbents is now being widely considered as an alternative, potentially less-energy-intensive separation technology. This Review describes the CO(2) adsorption behavior of several different classes of solid carbon dioxide adsorbents, including zeolites, activated carbons, calcium oxides, hydrotalcites, organic-inorganic hybrids, and metal-organic frameworks. These adsorbents are evaluated in terms of their equilibrium CO(2) capacities as well as other important parameters such as adsorption-desorption kinetics, operating windows, stability, and regenerability. The scope of currently available CO(2) adsorbents and their critical properties that will ultimately affect their incorporation into large-scale separation processes is presented.
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            CO2 capture and separation technologies for end-of-pipe applications – A review

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              Polymeric CO2/N2 gas separation membranes for the capture of carbon dioxide from power plant flue gases

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                Author and article information

                Journal
                ScientificWorldJournal
                ScientificWorldJournal
                TSWJ
                The Scientific World Journal
                Hindawi Publishing Corporation
                1537-744X
                2014
                17 February 2014
                : 2014
                : 828131
                Affiliations
                1Department of Chemical Engineering, Amirkabir University of Technology, P.O. Box 15875-4413, Tehran, Iran
                2Catalyst Research Group, Petrochemical Research and Technology Company, National Petrochemical Company, P.O. Box 1435884711, Tehran, Iran
                3Department of Petroleum Engineering, Petroleum University of Technology, P.O. Box 6198144471, Ahwaz, Iran
                Author notes
                *Mansooreh Soleimani: soleimanim@ 123456aut.ac.ir

                Academic Editors: D.-W. Han and V. A. Rogov

                Article
                10.1155/2014/828131
                3947793
                c7606cc4-1e49-4956-9055-8dc3522a2972
                Copyright © 2014 Mohammad Songolzadeh et al.

                This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                : 17 August 2013
                : 31 October 2013
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