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      Cyclic Distiba- and Dibismadiazenium Cations

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      Angewandte Chemie International Edition
      Wiley

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          Molecular double-bond covalent radii for elements Li-E112.

          The previous systems of triple-bond and single-bond self-consistent, additive covalent radii, R(AB)=r(A)+ r(B), are completed with a fit for sigma(2)pi(2) double-bonds.The primary bond lengths, R, are taken from experimental or theoretical data corresponding to chosen group valencies. All r(E) values are obtained from the same, self-consistent fit. Many of the calculated primary data came from E=CH(2) and H-E=CH(2) models. Homonuclear LE=EL, formaldehyde-type Group 14-Group 16 and open-shell, X (3) Sigma Group-16 dimer data are included. The standard deviation for the 316 included data points is 3 pm.
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            Analysis of the geometry of the hydroxymethyl radical by the “different hybrids for different spins” natural bond orbital procedure

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              Lehrbuch der Anorganischen Chemie

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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley
                14337851
                August 06 2012
                August 06 2012
                July 05 2012
                : 51
                : 32
                : 8087-8091
                Article
                10.1002/anie.201203267
                c886d23a-207b-4045-9586-0c4b50aee858
                © 2012

                http://doi.wiley.com/10.1002/tdm_license_1.1

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