Hydrological calibration of raw weather radar rainfall estimation relies on in situ rainfall measurements. Raindrop size distribution (DSD) was collected during three typical Mei-Yu rainstorms in July 2014 using three particle size velocity (Parsivel) DSD sensors along the Mei-Yu front in Nanjing, Chuzhou, and the western Pacific, respectively. To improve the radar precipitation estimation in different parts of the Mei-Yu front, a scaling method was adopted to formulate the DSD model and further derive the Z– R relations. The results suggest a distinct variation of DSDs in different parts of the Mei-Yu front. Compared with statistical radar Z–A R b relations obtained by mathematical fitting techniques, the use of a DSD model fitting based on a scaling law formulation theoretically shows a significant improvement in both stratiform (33.9%) and convective (2.8%) rainfall estimations of the Mei-Yu frontal system, which indicates that using a scaling law can better reflect the DSD variations in different parts of the Mei-Yu front. Polarimetric radar has indisputable advantages with multiparameter detection ability. Several dual-polarization radar estimators are also established by DSD sensor data, and the R( Z H , Z DR ) estimator is proven to be more accurate than traditional Z–R relations in Mei-Yu frontal rainfall, with potential applications for operational C-band polarimetric radar.