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      Colloidally prepared La-doped BaSnO 3 electrodes for efficient, photostable perovskite solar cells

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          Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers.

           W Chen,  Y. Wu,  Y. Yue (2015)
          The recent dramatic rise in power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) has triggered intense research worldwide. However, high PCE values have often been reached with poor stability at an illuminated area of typically less than 0.1 square centimeter. We used heavily doped inorganic charge extraction layers in planar PSCs to achieve very rapid carrier extraction, even with 10- to 20-nanometer-thick layers, avoiding pinholes and eliminating local structural defects over large areas. The robust inorganic nature of the layers allowed for the fabrication of PSCs with an aperture area >1 square centimeter that have a PCE >15%, as certified by an accredited photovoltaic calibration laboratory. Hysteresis in the current-voltage characteristics was eliminated; the PSCs were stable, with >90% of the initial PCE remaining after 1000 hours of light soaking.
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            Improving efficiency and stability of perovskite solar cells with photocurable fluoropolymers

            Organometal halide perovskite solar cells have demonstrated high conversion efficiency but poor long-term stability against ultraviolet irradiation and water. We show that rapid light-induced free-radical polymerization at ambient temperature produces multifunctional fluorinated photopolymer coatings that confer luminescent and easy-cleaning features on the front side of the devices, while concurrently forming a strongly hydrophobic barrier toward environmental moisture on the back contact side. The luminescent photopolymers re-emit ultraviolet light in the visible range, boosting perovskite solar cells efficiency to nearly 19% under standard illumination. Coated devices reproducibly retain their full functional performance during prolonged operation, even after a series of severe aging tests carried out for more than 6 months.
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              11% Efficient Perovskite Solar Cell Based on ZnO Nanorods: An Effective Charge Collection System

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                Author and article information

                Journal
                Science
                Science
                American Association for the Advancement of Science (AAAS)
                0036-8075
                1095-9203
                April 13 2017
                April 14 2017
                : 356
                : 6334
                : 167-171
                Article
                10.1126/science.aam6620
                28360134
                © 2017

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