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      Single-Crystal-to-Single-Crystal Transformation of a Europium(III) Metal-Organic Framework Producing a Multi-responsive Luminescent Sensor

      , , , , , , ,

      Advanced Functional Materials

      Wiley-Blackwell

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          Functional Porous Coordination Polymers

          The chemistry of the coordination polymers has in recent years advanced extensively, affording various architectures, which are constructed from a variety of molecular building blocks with different interactions between them. The next challenge is the chemical and physical functionalization of these architectures, through the porous properties of the frameworks. This review concentrates on three aspects of coordination polymers: 1). the use of crystal engineering to construct porous frameworks from connectors and linkers ("nanospace engineering"), 2). characterizing and cataloging the porous properties by functions for storage, exchange, separation, etc., and 3). the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli. Our aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers.
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            Single-crystal structure validation with the programPLATON

             A. Spek (2003)
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              Metal-organic frameworks for separations.

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                Author and article information

                Journal
                Advanced Functional Materials
                Adv. Funct. Mater.
                Wiley-Blackwell
                1616301X
                July 2014
                July 18 2014
                : 24
                : 26
                : 4034-4041
                Article
                10.1002/adfm.201303986
                © 2014

                http://doi.wiley.com/10.1002/tdm_license_1.1

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