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      Photoresponsive Block Copolymers Containing Azobenzenes and Other Chromophores

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          Abstract

          Photoresponsive block copolymers (PRBCs) containing azobenzenes and other chromophores can be easily prepared by controlled polymerization. Their photoresponsive behaviors are generally based on photoisomerization, photocrosslinking, photoalignment and photoinduced cooperative motions. When the photoactive block forms mesogenic phases upon microphase separation of PRBCs, supramolecular cooperative motion in liquid-crystalline PRBCs enables them to self-organize into hierarchical structures with photoresponsive features. This offers novel opportunities to photocontrol microphase-separated nanostructures of well-defined PRBCs and extends their diverse applications in holograms, nanotemplates, photodeformed devices and microporous films.

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          Most cited references121

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          Polymer vesicles.

          Vesicles are microscopic sacs that enclose a volume with a molecularly thin membrane. The membranes are generally self-directed assemblies of amphiphilic molecules with a dual hydrophilic-hydrophobic character. Biological amphiphiles form vesicles central to cell function and are principally lipids of molecular weight less than 1 kilodalton. Block copolymers that mimic lipid amphiphilicity can also self-assemble into vesicles in dilute solution, but polymer molecular weights can be orders of magnitude greater than those of lipids. Structural features of vesicles, as well as properties including stability, fluidity, and intermembrane dynamics, are greatly influenced by characteristics of the polymers. Future applications of polymer vesicles will rely on exploiting unique property-performance relations, but results to date already underscore the fact that biologically derived vesicles are but a small subset of what is physically and chemically possible.
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            Block Copolymers—Designer Soft Materials

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              Photoinduced motions in azo-containing polymers.

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                Author and article information

                Journal
                Molecules
                Molecules
                molecules
                Molecules
                Molecular Diversity Preservation International
                1420-3049
                26 January 2010
                January 2010
                : 15
                : 1
                : 570-603
                Affiliations
                [1 ]Top Runner Incubation Center for Academia-Industry Fusion, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka 940-2188, Japan
                [2 ]Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka 940-2188, Japan; E-Mail: takaomi@ 123456nagaokaut.ac.jp
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: yuhaifeng@ 123456mst.nagaokaut.ac.jp ; Tel.: +81 0258-47-9310; Fax: +81 0258-47-9300.
                Article
                molecules-15-00570
                10.3390/molecules15010570
                6256985
                20110910
                d21f5c62-d58c-4e69-86c1-b596f66e8934
                © 2010 by the authors;

                licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/).

                History
                : 25 December 2009
                : 11 January 2010
                : 25 January 2010
                Categories
                Review

                photoresponsive block copolymers,microphase separation,azobenzenes,liquid crystals,advanced materials

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