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      Realizing room-temperature self-powered ethanol sensing of ZnO nanowire arrays by combining their piezoelectric, photoelectric and gas sensing characteristics

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          Abstract

          Room-temperature self-powered ethanol sensing has been realized from ZnO nanowire arrays by combining their piezoelectric, photoelectric and gas sensing characteristics.

          Abstract

          Room-temperature self-powered ethanol sensing has been realized from ZnO nanowire (NW) arrays by combining their piezoelectric, photoelectric and gas sensing characteristics. Under the assistance of UV illumination, the piezoelectric output of ZnO NWs acts not only as a power source, but also as a response signal to ethanol gas at room temperature. Upon exposure to 700 ppm ethanol at room temperature under 67.5 mW cm −2 UV illumination, the piezoelectric output voltage of ZnO NWs (under 34 N compressive forces) decreases from 0.80 V (in air) to 0.12 V and the response is up to 85. The room-temperature reaction between the UV-induced chemisorbed oxygen ions and ethanol molecules increases the carrier density in ZnO NWs, resulting in a strong piezoelectric screening effect and very low piezoelectric output. Our study can stimulate a research trend on designing new gas sensors and investigating new gas sensing mechanisms.

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          Most cited references46

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          Nanotube molecular wires as chemical sensors

          Chemical sensors based on individual single-walled carbon nanotubes (SWNTs) are demonstrated. Upon exposure to gaseous molecules such as NO(2) or NH(3), the electrical resistance of a semiconducting SWNT is found to dramatically increase or decrease. This serves as the basis for nanotube molecular sensors. The nanotube sensors exhibit a fast response and a substantially higher sensitivity than that of existing solid-state sensors at room temperature. Sensor reversibility is achieved by slow recovery under ambient conditions or by heating to high temperatures. The interactions between molecular species and SWNTs and the mechanisms of molecular sensing with nanotube molecular wires are investigated.
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            Oxygen vacancies in ZnO

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              Piezoelectric field effect transistor and nanoforce sensor based on a single ZnO nanowire.

              Utilizing the coupled piezoelectric and semiconducting dual properties of ZnO, we demonstrate a piezoelectric field effect transistor (PE-FET) that is composed of a ZnO nanowire (NW) (or nanobelt) bridging across two Ohmic contacts, in which the source to drain current is controlled by the bending of the NW. A possible mechanism for the PE-FET is suggested to be associated with the carrier trapping effect and the creation of a charge depletion zone under elastic deformatioin. This PE-FET has been applied as a force/pressure sensor for measuring forces in the nanonewton range and even smaller with the use of smaller NWs. An almost linear relationship between the bending force and the conductance was found at small bending regions, demonstrating the principle of nanowire-based nanoforce and nanopressure sensors.
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                Author and article information

                Journal
                JMCAET
                Journal of Materials Chemistry A
                J. Mater. Chem. A
                Royal Society of Chemistry (RSC)
                2050-7488
                2050-7496
                2015
                2015
                : 3
                : 7
                : 3529-3535
                Article
                10.1039/C4TA06266C
                d3c8832f-cb59-4ec4-af3e-2d584f55ce77
                © 2015
                History

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