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      Organosilica Membrane with Ionic Liquid Properties for Separation of Toluene/H 2 Mixture

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          Abstract

          In this study, we present a new concept in chemically stabilized ionic liquid membranes: an ionic liquid organosilica (ILOS) membrane, which is an organosilica membrane with ionic liquid-like properties. A silylated ionic liquid was used as a precursor for synthesis. The permselectivity, permeation mechanism, and stability of the membrane in the H 2/toluene binary system were then compared with a supported ionic liquid membrane. The membrane showed a superior separation factor of toluene/H 2 (>17,000) in a binary mixture system based on a solution–diffusion mechanism with improved durability over the supported ionic liquid membrane.

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          CO2Capture by a Task-Specific Ionic Liquid

          Eleanor Bates, Rebecca Mayton, Ioanna Ntai … (2002)
          Article 0 comments Cited 318 times – based on 0 reviews     Review now
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            Gas separations using non-hexafluorophosphate [PF6]− anion supported ionic liquid membranes

            R. Noble, P SCOVAZZO, J KIEFT … (2004)
            Article 0 comments Cited 56 times – based on 0 reviews     Review now
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              Chemical hydrides: A solution to high capacity hydrogen storage and supply

              S. Rayalu, R. B. Biniwale, M Ichikawa … (2008)
              Article 0 comments Cited 51 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Journal ID (nlm-ta): Materials (Basel)
                Journal ID (iso-abbrev): Materials (Basel)
                Journal ID (publisher-id): materials
                Title: Materials
                Publisher: MDPI
                ISSN (Electronic): 1996-1944
                Publication date (Electronic): 03 August 2017
                Publication date Collection: August 2017
                Volume: 10
                Issue: 8
                Electronic Location Identifier: 901
                Affiliations
                [1 ]Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan; ymaeda@ 123456cheng.es.osaka-u.ac.jp (Y.M.); y.yamamoto@ 123456cheng.es.osaka-u.ac.jp (Y.Y.); nisiyama@ 123456cheng.es.osaka-u.ac.jp (N.N.)
                [2 ]Department of Chemistry and Biomolecular Science, Gifu University, 1-1 Yanagido, Gifu 501-1193, Japan; m_miya@ 123456gifu-u.ac.jp
                Author notes
                [* ]Correspondence: yhirota@ 123456cheng.es.osaka-u.ac.jp ; Tel.: +81-6-6850-6257
                Author information
                https://orcid.org/0000-0002-2397-249X
                Article
                Publisher ID: materials-10-00901
                DOI: 10.3390/ma10080901
                PMC ID: 5578267
                PubMed ID: 28771202
                SO-VID: d431444a-6fa6-410e-8078-9a38db5cd62a
                Copyright © © 2017 by the authors.
                License:

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                Date received : 10 June 2017
                Date accepted : 02 August 2017
                Categories
                Subject: Communication

                Keywords: organosilica membrane,ionic liquid,hydrogen purification,organic chemical hydride,hydrocarbon separation
                Data availability:
                Keywords: organosilica membrane, ionic liquid, hydrogen purification, organic chemical hydride, hydrocarbon separation

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