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      Synthesis of Carbon Nanotubes from Graphite and Investigation of the Catalytic Activity of MWCNTs/Cr2O3–NiO with the Removal of Bismarсk Brown G Dye from Its Aqueous Solution

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      Ukrainian Journal of Physics
      National Academy of Sciences of Ukraine (Co. LTD Ukrinformnauka)

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          Abstract

          This work describes the synthesis of carbon nanotubes from graphite by the chemical precipitation method and nanocomposites of multiwall carbon nanotubes (MWCNTs) with co-oxide nanocomposite (MWCNTs)/MO(Cr2O3–NiO). Those nanocomposites were prepared with the use of a simple evaporation and a drying process. The obtained composites were characterized, by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy. The activity of the prepared composites was investigated by the following removal of a Bismarck brown G dye (BBG) from the aqueous solution via photocatalytic reactions. The efficiency of the photocatalytic dye removal over the prepared composites was 91.43% after one hour of reaction under the optimal conditions, which were a mass dosage of 0.03 g, pH = 5, and a temperature of 30 ∘C.

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          Size matters: why nanomaterials are different.

          Gold is known as a shiny, yellow noble metal that does not tarnish, has a face centred cubic structure, is non-magnetic and melts at 1336 K. However, a small sample of the same gold is quite different, providing it is tiny enough: 10 nm particles absorb green light and thus appear red. The melting temperature decreases dramatically as the size goes down. Moreover, gold ceases to be noble, and 2-3 nm nanoparticles are excellent catalysts which also exhibit considerable magnetism. At this size they are still metallic, but smaller ones turn into insulators. Their equilibrium structure changes to icosahedral symmetry, or they are even hollow or planar, depending on size. The present tutorial review intends to explain the origin of this special behaviour of nanomaterials.
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            Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal.

            Alumina-coated multi-wall carbon nanotubes were synthesized and characterized by scanning electron microscopy, X-ray diffraction, and FTIR. They were used as an adsorbent for the removal of lead ions from aqueous solutions in two modes, batch and fixed bed. In the batch mode, experiments were carried out to investigate the effect of contact time, agitation speed, adsorbent dosage and solution pH on the removal of lead. The coated nanotubes exhibit better removal ability over uncoated. For fixed-bed columns, thickness of the layer and flow rate were investigated. Increasing the thickness and decreasing the flow rate enhanced the removal of lead. The prepared adsorbent displayed the main advantage of separation convenience when a fixed-bed column was used compared to the batch adsorption treatment. Copyright © 2010 Elsevier B.V. All rights reserved.
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              New Insight for Enhanced Photocatalytic Activity of TiO2by Doping Carbon Nanotubes: A Case Study on Degradation of Benzene and Methyl Orange

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                Author and article information

                Journal
                Ukrainian Journal of Physics
                Ukr. J. Phys.
                National Academy of Sciences of Ukraine (Co. LTD Ukrinformnauka)
                2071-0194
                2071-0186
                May 16 2019
                May 16 2019
                : 64
                : 4
                : 276
                Article
                10.15407/ujpe64.4.276
                d7d58bd8-135b-45e6-b298-badb4baef5b4
                © 2019
                History

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