8
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: found
      • Article: not found

      Base-mediated conversion of hydrazine to diazene and dinitrogen at an iron center.

      Inorganic Chemistry
      Hydrazines, chemistry, Imides, Iron, Magnetic Resonance Spectroscopy, Models, Molecular, Molecular Conformation, Nitrogen, Organometallic Compounds, chemical synthesis

      Read this article at

      ScienceOpenPublisherPubMed
      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          The treatment of the hydrazine complex cis-[Fe(N(2)H(4))(dmpe)(2)](2+) with base afforded the diazene complex cis-[Fe(N(2)H(2))(dmpe)(2)]. This reaction is reversed by the treatment of the diazene complex with a mild acid, while treatment of the hydrazine complex with a mixture of KOBu(t) and Bu(t)Li afforded the dinitrogen complex [Fe(N(2))(dmpe)(2)].

          Related collections

          Author and article information

          Comments

          Comment on this article