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      Oil/water separation techniques: a review of recent progresses and future directions

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          Abstract

          The recent progress of oil/water separation technologies using various materials that possess surface superwetting properties is summarized.

          Abstract

          Oil/water separation is a field of high significance as it has direct practical implications for resolving the problem of industrial oily wastewater and other oil/water pollution. Therefore, the development of functional materials for efficient treatment of oil-polluted water is imperative. In this feature article, we have reviewed the recent progress of oil/water separation technologies based on filtration and absorption methods using various materials that possess surface superwetting properties. In each section, we present in detail representative work and describe the concepts, employed materials, fabrication methods, and the effects of their wetting/dewetting behaviors on oil/water separation. Finally, the challenges and future research directions of this promising research field are briefly discussed.

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          Most cited references205

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          Electrospinning of Nanofibers: Reinventing the Wheel?

          D Li, Y Xia (2004)
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            Designing superoleophobic surfaces.

            Understanding the complementary roles of surface energy and roughness on natural nonwetting surfaces has led to the development of a number of biomimetic superhydrophobic surfaces, which exhibit apparent contact angles with water greater than 150 degrees and low contact angle hysteresis. However, superoleophobic surfaces-those that display contact angles greater than 150 degrees with organic liquids having appreciably lower surface tensions than that of water-are extremely rare. Calculations suggest that creating such a surface would require a surface energy lower than that of any known material. We show how a third factor, re-entrant surface curvature, in conjunction with chemical composition and roughened texture, can be used to design surfaces that display extreme resistance to wetting from a number of liquids with low surface tension, including alkanes such as decane and octane.
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              Candle soot as a template for a transparent robust superamphiphobic coating.

              Coating is an essential step in adjusting the surface properties of materials. Superhydrophobic coatings with contact angles greater than 150° and roll-off angles below 10° for water have been developed, based on low-energy surfaces and roughness on the nano- and micrometer scales. However, these surfaces are still wetted by organic liquids such as surfactant-based solutions, alcohols, or alkanes. Coatings that are simultaneously superhydrophobic and superoleophobic are rare. We designed an easily fabricated, transparent, and oil-rebounding superamphiphobic coating. A porous deposit of candle soot was coated with a 25-nanometer-thick silica shell. The black coating became transparent after calcination at 600°C. After silanization, the coating was superamphiphobic and remained so even after its top layer was damaged by sand impingement.

                Author and article information

                Journal
                JMCAET
                Journal of Materials Chemistry A
                J. Mater. Chem. A
                Royal Society of Chemistry (RSC)
                2050-7488
                2050-7496
                2017
                2017
                : 5
                : 31
                : 16025-16058
                Affiliations
                [1 ]Department of Chemical Engineering
                [2 ]Indian Institute of Technology Kanpur
                [3 ]Kanpur – 208016
                [4 ]India
                [5 ]Center for Nanosciences
                [6 ]Department of Chemistry
                [7 ]University of Sheffield
                [8 ]Sheffield
                [9 ]UK
                [10 ]National Institute of Advanced Industrial Science and Technology (AIST)
                [11 ]Nagoya 463-8560
                [12 ]Japan
                Article
                10.1039/C7TA02070H
                d841bdbf-886e-4a9c-a1bd-0c364c313e54
                © 2017
                History

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