64
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: found
      • Article: found
      Is Open Access

      Dye-Sensitized Solar Cells: Fundamentals and Current Status

      review-article

      Read this article at

      ScienceOpenPublisherPMC
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          Dye-sensitized solar cells (DSSCs) belong to the group of thin-film solar cells which have been under extensive research for more than two decades due to their low cost, simple preparation methodology, low toxicity and ease of production. Still, there is lot of scope for the replacement of current DSSC materials due to their high cost, less abundance, and long-term stability. The efficiency of existing DSSCs reaches up to 12%, using Ru(II) dyes by optimizing material and structural properties which is still less than the efficiency offered by first- and second-generation solar cells, i.e., other thin-film solar cells and Si-based solar cells which offer ~ 20–30% efficiency. This article provides an in-depth review on DSSC construction, operating principle, key problems (low efficiency, low scalability, and low stability), prospective efficient materials, and finally a brief insight to commercialization.

          Related collections

          Most cited references418

          • Record: found
          • Abstract: found
          • Article: not found

          Porphyrin-sensitized solar cells with cobalt (II/III)-based redox electrolyte exceed 12 percent efficiency.

          The iodide/triiodide redox shuttle has limited the efficiencies accessible in dye-sensitized solar cells. Here, we report mesoscopic solar cells that incorporate a Co((II/III))tris(bipyridyl)-based redox electrolyte in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer (designated YD2-o-C8). The specific molecular design of YD2-o-C8 greatly retards the rate of interfacial back electron transfer from the conduction band of the nanocrystalline titanium dioxide film to the oxidized cobalt mediator, which enables attainment of strikingly high photovoltages approaching 1 volt. Because the YD2-o-C8 porphyrin harvests sunlight across the visible spectrum, large photocurrents are generated. Cosensitization of YD2-o-C8 with another organic dye further enhances the performance of the device, leading to a measured power conversion efficiency of 12.3% under simulated air mass 1.5 global sunlight.
            • Record: found
            • Abstract: not found
            • Article: not found

            A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films

              • Record: found
              • Abstract: found
              • Article: not found

              Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers.

              Dye-sensitized solar cells have gained widespread attention in recent years because of their low production costs, ease of fabrication and tunable optical properties, such as colour and transparency. Here, we report a molecularly engineered porphyrin dye, coded SM315, which features the prototypical structure of a donor-π-bridge-acceptor and both maximizes electrolyte compatibility and improves light-harvesting properties. Linear-response, time-dependent density functional theory was used to investigate the perturbations in the electronic structure that lead to improved light harvesting. Using SM315 with the cobalt(II/III) redox shuttle resulted in dye-sensitized solar cells that exhibit a high open-circuit voltage VOC of 0.91 V, short-circuit current density JSC of 18.1 mA cm(-2), fill factor of 0.78 and a power conversion efficiency of 13%.

                Author and article information

                Contributors
                sharma.k.ajm@gmail.com
                VINAYKUM002@e.ntu.edu.sg
                sharmass2@gmail.com
                Journal
                Nanoscale Res Lett
                Nanoscale Res Lett
                Nanoscale Research Letters
                Springer US (New York )
                1931-7573
                1556-276X
                28 November 2018
                28 November 2018
                2018
                : 13
                : 381
                Affiliations
                [1 ]GRID grid.449468.3, Department of Physics, , Bhagwant University, ; Ajmer, 305004 India
                [2 ]ISNI 0000 0001 2224 0361, GRID grid.59025.3b, School of Materials Science and Engineering, , Nanyang Technological University, ; Singapore, 639798 Singapore
                [3 ]ISNI 0000 0000 8498 7826, GRID grid.412746.2, Department of Physics, , Govt. Women Engineering College, ; Ajmer, 305002 India
                Article
                2760
                10.1186/s11671-018-2760-6
                6261913
                30488132
                d858f446-ef70-40f8-9259-59ff1611c6b8
                © The Author(s). 2018

                Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License ( http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

                History
                : 22 September 2017
                : 17 October 2018
                Funding
                Funded by: FundRef http://dx.doi.org/10.13039/501100001843, Science and Engineering Research Board;
                Award ID: SR/FTP/PS-112/2012
                Categories
                Nano Review
                Custom metadata
                © The Author(s) 2018

                Nanomaterials
                dye-sensitized solar cells (dsscs),photoanode,counter electrode,electrolytes,metal and metal-free organic dyes,efficiency,stability

                Comments

                Comment on this article

                Related Documents Log