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      Geochemical Exports to River From the Intrameander Hyporheic Zone Under Transient Hydrologic Conditions: East River Mountainous Watershed, Colorado

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          THE ECOLOGY OF INTERFACES:Riparian Zones

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            Dynamics of nitrate production and removal as a function of residence time in the hyporheic zone

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              Inorganic species in geologic fluids: correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes.

              Correlations among experimentally determined standard partial molal thermodynamic properties of inorganic aqueous species at 25 degrees C and 1 bar allow estimates of these properties for numerous monatomic cations and anions, polyatomic anions, oxyanions, acid oxyanions, neutral oxy-acid species, dissolved gases, and hydroxide complexes of metal cations. Combined with correlations among parameters in the revised Helgeson-Kirkham-Flowers (HKF) equation of state (Shock et al., 1992), these estimates permit predictions of standard partial molal volumes, heat capacities, and entropies, as well as apparent standard partial molal enthalpies and Gibbs free energies of formation to 1000 degrees C and 5 kb for hundreds of inorganic aqueous species of interest in geochemistry. Data and parameters for more than 300 inorganic aqueous species are presented. Close agreement between calculated and experimentally determined equilibrium constants for acid dissociation reactions and cation hydrolysis reactions supports the generality and validity of these predictive methods. These data facilitate the calculation of the speciation of major, minor, and trace elements in hydrothermal and metamorphic fluids throughout most of the crust of the Earth.
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                Author and article information

                Journal
                Water Resources Research
                Water Resour. Res.
                American Geophysical Union (AGU)
                0043-1397
                1944-7973
                October 20 2018
                October 2018
                October 30 2018
                October 2018
                : 54
                : 10
                : 8456-8477
                Affiliations
                [1 ]Earth and Environmental Sciences Area, Geochemistry DepartmentLawrence Berkeley National Laboratory Berkeley CA USA
                [2 ]Applied Mathematics and Plasma PhysicsLos Alamos National Laboratory Los Alamos NM USA
                [3 ]Division of Hydrologic SciencesThe Desert Research Institute Reno NV USA
                Article
                10.1029/2018WR023377
                © 2018

                http://onlinelibrary.wiley.com/termsAndConditions#am

                http://onlinelibrary.wiley.com/termsAndConditions#vor

                http://doi.wiley.com/10.1002/tdm_license_1.1

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