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      A primeira lei da termodinâmica dos processos homogêneos Translated title: The first law of homogeneous processes thermodynamics

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          Translated abstract

          Thermodynamics of homogeneous processes, which corresponds to the very special situation in thermodynamics of continuous media, is used to discuss the first law. An important part of this work is the exposition of some typical mathematical errors, frequently found in the traditional presentation of thermodynamics. The concepts of state and process functions are discussed, as well as reverse and reversible processes, temporality and its implications on thermodynamics, energy reservoirs and symmetry. Our proposal is to present the first law by using a time dependent viewpoint coherent with mechanics and the foundations of that viewpoint.

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          Most cited references33

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          Rational Thermodynamics

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            The Mechanics and Thermodynamics of Continuous Media

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              An Introduction to Statistical Thermodynamics

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                Author and article information

                Contributors
                Role: ND
                Role: ND
                Journal
                qn
                Química Nova
                Quím. Nova
                Sociedade Brasileira de Química (São Paulo )
                1678-7064
                2009
                : 32
                : 2
                : 522-529
                Affiliations
                [1 ] Universidade Estadual de Campinas Brazil
                Article
                S0100-40422009000200042
                10.1590/S0100-40422009000200042
                da21b517-2776-4c59-a2c2-061b8d6db86f

                http://creativecommons.org/licenses/by/4.0/

                History
                Product

                SciELO Brazil

                Self URI (journal page): http://www.scielo.br/scielo.php?script=sci_serial&pid=0100-4042&lng=en
                Categories
                CHEMISTRY, MULTIDISCIPLINARY

                General chemistry
                first law of thermodynamics,reversible processes,time dependent thermodynamics

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