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      Arsenic Contamination of Groundwater: A Review of Sources, Prevalence, Health Risks, and Strategies for Mitigation

      review-article
      1 , 2 , * , 1
      The Scientific World Journal
      Hindawi Publishing Corporation

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          Abstract

          Arsenic contamination of groundwater in different parts of the world is an outcome of natural and/or anthropogenic sources, leading to adverse effects on human health and ecosystem. Millions of people from different countries are heavily dependent on groundwater containing elevated level of As for drinking purposes. As contamination of groundwater, poses a serious risk to human health. Excessive and prolonged exposure of inorganic As with drinking water is causing arsenicosis, a deteriorating and disabling disease characterized by skin lesions and pigmentation of the skin, patches on palm of the hands and soles of the feet. Arsenic poisoning culminates into potentially fatal diseases like skin and internal cancers. This paper reviews sources, speciation, and mobility of As and global overview of groundwater As contamination. The paper also critically reviews the As led human health risks, its uptake, metabolism, and toxicity mechanisms. The paper provides an overview of the state-of-the-art knowledge on the alternative As free drinking water and various technologies (oxidation, coagulation flocculation, adsorption, and microbial) for mitigation of the problem of As contamination of groundwater.

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          Arsenic removal from water/wastewater using adsorbents--A critical review.

          Arsenic's history in science, medicine and technology has been overshadowed by its notoriety as a poison in homicides. Arsenic is viewed as being synonymous with toxicity. Dangerous arsenic concentrations in natural waters is now a worldwide problem and often referred to as a 20th-21st century calamity. High arsenic concentrations have been reported recently from the USA, China, Chile, Bangladesh, Taiwan, Mexico, Argentina, Poland, Canada, Hungary, Japan and India. Among 21 countries in different parts of the world affected by groundwater arsenic contamination, the largest population at risk is in Bangladesh followed by West Bengal in India. Existing overviews of arsenic removal include technologies that have traditionally been used (oxidation, precipitation/coagulation/membrane separation) with far less attention paid to adsorption. No previous review is available where readers can get an overview of the sorption capacities of both available and developed sorbents used for arsenic remediation together with the traditional remediation methods. We have incorporated most of the valuable available literature on arsenic remediation by adsorption ( approximately 600 references). Existing purification methods for drinking water; wastewater; industrial effluents, and technological solutions for arsenic have been listed. Arsenic sorption by commercially available carbons and other low-cost adsorbents are surveyed and critically reviewed and their sorption efficiencies are compared. Arsenic adsorption behavior in presence of other impurities has been discussed. Some commercially available adsorbents are also surveyed. An extensive table summarizes the sorption capacities of various adsorbents. Some low-cost adsorbents are superior including treated slags, carbons developed from agricultural waste (char carbons and coconut husk carbons), biosorbents (immobilized biomass, orange juice residue), goethite and some commercial adsorbents, which include resins, gels, silica, treated silica tested for arsenic removal come out to be superior. Immobilized biomass adsorbents offered outstanding performances. Desorption of arsenic followed by regeneration of sorbents has been discussed. Strong acids and bases seem to be the best desorbing agents to produce arsenic concentrates. Arsenic concentrate treatment and disposal obtained is briefly addressed. This issue is very important but much less discussed.
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            Arsenic speciation in the environment

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              Public health. Worldwide occurrences of arsenic in ground water.

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                Author and article information

                Journal
                ScientificWorldJournal
                ScientificWorldJournal
                TSWJ
                The Scientific World Journal
                Hindawi Publishing Corporation
                2356-6140
                1537-744X
                2014
                14 October 2014
                : 2014
                : 304524
                Affiliations
                1Babasaheb Bhimrao Ambedkar University, Lucknow 226025, India
                2Department of Chemistry, Dr. B. R. Ambedkar National Institute of Technology Jalandhar, Punjab 144011, India
                Author notes

                Academic Editor: Andrei Surguchov

                Author information
                http://orcid.org/0000-0001-8082-8243
                http://orcid.org/0000-0002-2448-3604
                Article
                10.1155/2014/304524
                4211162
                dc1d063f-167b-47be-b66c-2ede5480b64d
                Copyright © 2014 Shiv Shankar et al.

                This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                : 2 July 2014
                : 17 August 2014
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