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      Synthesis, properties and performance of organic polymers employed in flocculation applications

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      Polymer Chemistry
      Royal Society of Chemistry (RSC)

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          Abstract

          Recent developments on the synthesis and flocculation efficiency of several non-ionic, cationic, anionic and amphoteric polymers are presented and summarised.

          Flocculation is a common technique that is widely used in many industrial applications to promote solid–liquid separation processes. The addition of a polymeric flocculant allows for the destabilization of suspended colloidal particles, and thus significantly increases their sedimentation rate. Polymeric flocculants are generally divided into four categories, which include non-ionic, cationic, anionic, and amphoteric polymers. This minireview article summarises important information on the recent design and synthesis of polymeric materials from these four categories. In addition, their properties and flocculation efficiency are also presented and discussed.

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          Organic polyelectrolytes in water treatment.

          The use of polymers in the production of drinking water is reviewed, with emphasis on the nature of the impurities to be removed, the mechanisms of coagulation and flocculation, and the types of polymers commonly available. There is a focus on polymers for primary coagulation, their use as coagulant aids, in the recycling of filter backwash waters, and in sludge thickening. Practicalities of polymer use are discussed, with particular attention to polymer toxicity, and the presence of residual polymer in the final drinking water. The questions of polymer degradation and the formation of disinfection by-products are also addressed.
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            A review on application of flocculants in wastewater treatment

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              Adsorption and flocculation by polymers and polymer mixtures.

              Polymers of various types are in widespread use as flocculants in several industries. In most cases, polymer adsorption is an essential prerequisite for flocculation and kinetic aspects are very important. The rates of polymer adsorption and of re-conformation (relaxation) of adsorbed chains are key factors that influence the performance of flocculants and their mode of action. Polyelectrolytes often tend to adopt a rather flat adsorbed configuration and in this state their action is mainly through charge effects, including 'electrostatic patch' attraction. When the relaxation rate is quite low, particle collisions may occur while the adsorbed chains are still in an extended state and flocculation by polymer bridging may occur. These effects are now well understood and supported by much experimental evidence. In recent years there has been considerable interest in the use of multi-component flocculants, especially dual-polymer systems. In the latter case, there can be significant advantages over the use of single polymers. Despite some complications, there is a broad understanding of the action of dual polymer systems. In many cases the sequence of addition of the polymers is important and the pre-adsorbed polymer can have two important effects: providing adsorption sites for the second polymer or causing a more extended adsorbed conformation as a result of 'site blocking'.
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                Author and article information

                Journal
                PCOHC2
                Polymer Chemistry
                Polym. Chem.
                Royal Society of Chemistry (RSC)
                1759-9954
                1759-9962
                2016
                2016
                : 7
                : 1
                : 11-25
                Article
                10.1039/C5PY01572C
                e10afb5c-d740-4b04-8bd2-ece89958fde2
                © 2016
                History

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