Visible light-mediated oxidative C(sp <sup>3</sup>)–H phosphonylation for α-aminophosphonates under oxidant-free conditions

Author(s): Linbin Niu ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Shengchun Wang ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Jiamei Liu ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Hong Yi ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Xing-An Liang ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Tianyi Liu ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Aiwen Lei ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵

Publication date (Electronic): 2018

Journal: Chemical Communications

Publisher: Royal Society of Chemistry (RSC)

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Abstract

An external oxidant-free synthesis of α-aminophosphonates by synergistically combining photocatalysis and proton-reduction catalysis is developed herein.

Abstract

An external oxidant-free synthesis of α-aminophosphonates by synergistically combining photocatalysis and proton-reduction catalysis is developed herein. The gram-scale experiment demonstrates the potential utility of this protocol. This study may have important implications for the functionalization of oxidant-sensitive C(sp ³)–H bonds.

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Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

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Visible light photoredox catalysis: applications in organic synthesis.

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The use of visible light sensitization as a means to initiate organic reactions is attractive due to the lack of visible light absorbance by organic compounds, reducing side reactions often associated with photochemical reactions conducted with high energy UV light. This tutorial review provides a historical overview of visible light photoredox catalysis in organic synthesis along with recent examples which underscore its vast potential to initiate organic transformations.

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Author and article information

Contributors

Aiwen Lei: (View ORCID Profile)

Journal

Journal ID (publisher-id): CHCOFS

Title: Chemical Communications

Abbreviated Title: Chem. Commun.

Publisher: Royal Society of Chemistry (RSC)

ISSN (Print): 1359-7345

ISSN (Electronic): 1364-548X

Publication date Created: 2018

Publication date (Electronic): 2018

Volume: 54

Issue: 13

Pages: 1659-1662

Affiliations

[1 ]College of Chemistry and Molecular Sciences

[2 ]Institute for Advanced Studies (IAS)

[3 ]Wuhan University

[4 ]Wuhan 430072

[5 ]P. R. China

Article

DOI: 10.1039/C7CC09624K

SO-VID: e2f640e8-e6dc-4590-a9ae-3f5178c7447d

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