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      Luminescent Materials: Locking π-Conjugated and Heterocyclic Ligands with Boron(III)

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      Angewandte Chemie International Edition

      Wiley-Blackwell

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          Principles of Fluorescence Spectroscopy

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            The chemistry of fluorescent bodipy dyes: versatility unsurpassed.

            The world of organic luminophores has been confined for a long time to fairly standard biological labeling applications and to certain analytical tests. Recently, however, the field has undergone a major change of direction, driven by the dual needs to develop novel organic electronic materials and to fuel the rapidly emerging nanotechnologies. Among the many diverse fluorescent molecules, the Bodipy family, first developed as luminescent tags and laser dyes, has become a cornerstone for these new applications. The near future looks extremely bright for "porphyrin's little sister".
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              Small molecule organic semiconductors on the move: promises for future solar energy technology.

              This article is written from an organic chemist's point of view and provides an up-to-date review about organic solar cells based on small molecules or oligomers as absorbers and in detail deals with devices that incorporate planar-heterojunctions (PHJ) and bulk heterojunctions (BHJ) between a donor (p-type semiconductor) and an acceptor (n-type semiconductor) material. The article pays particular attention to the design and development of molecular materials and their performance in corresponding devices. In recent years, a substantial amount of both, academic and industrial research, has been directed towards organic solar cells, in an effort to develop new materials and to improve their tunability, processability, power conversion efficiency, and stability. On the eve of commercialization of organic solar cells, this review provides an overview over efficiencies attained with small molecules/oligomers in OSCs and reflects materials and device concepts developed over the last decade. Approaches to enhancing the efficiency of organic solar cells are analyzed.
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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley-Blackwell
                14337851
                February 24 2014
                February 24 2014
                : 53
                : 9
                : 2290-2310
                Article
                10.1002/anie.201305554
                © 2014

                http://doi.wiley.com/10.1002/tdm_license_1.1

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