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      Electrochemical Deposition and Dissolution of Thallium from Sulfate Solutions

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          Abstract

          The electrochemical behavior of thallium was studied on glassy carbon electrodes in sulfate solutions. Cyclic voltammetry was used to study the kinetics of the electrode processes and to determine the nature of the limiting step of the cathodic reduction of thallium ions. According to the dependence of current on stirring rate and scan rate, this process is diffusion limited. Chronocoulometry showed that the electrodeposition can be performed with a current efficiency of up to 96% in the absence of oxygen.

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          Most cited references 18

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          Thallium poisoning.

           S MOESCHLIN (1980)
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            Simultaneous Determination of Thallium and Lead on a Chemically Modified Electrode with Langmuira€“ Blodgett Film of ap-tert-Butylcalix[4]arene Derivative

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              Vlianiya sostava rastvora na kinetiku aktivnogo rastvoreniya talliya

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                Author and article information

                Journal
                Int J Anal Chem
                Int J Anal Chem
                IJAC
                International Journal of Analytical Chemistry
                Hindawi Publishing Corporation
                1687-8760
                1687-8779
                2015
                3 May 2015
                : 2015
                Affiliations
                1Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71 Al-Farabi Avenue, Almaty 050040, Kazakhstan
                2Institut für Biochemie, Universität Greifswald, Soldmannstrasse 23, 17489 Greifswald, Germany
                Author notes
                *Ye. Zh. Ussipbekova: enlik-86taraz@ 123456mail.ru

                Academic Editor: Adil Denizli

                Article
                10.1155/2015/357514
                4433681
                Copyright © 2015 Ye. Zh. Ussipbekova et al.

                This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

                Categories
                Research Article

                Analytical chemistry

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