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Abstract

A simple and effective catalytic method to construct propargylamine was developed by using copper bromide and tert-BuOOH via a combination of sp3 C-H bond and sp C-H bond activations followed by C-C bond formation.

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PubMed ID:: 15382913

DOI:: 10.1021/ja0460763

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CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.

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