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      Application of Zn-ferrite towards thermochemical utilization of carbon dioxide: A thermodynamic investigation

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      Energy Conversion and Management
      Elsevier BV

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          High-flux solar-driven thermochemical dissociation of CO2 and H2O using nonstoichiometric ceria.

          Because solar energy is available in large excess relative to current rates of energy consumption, effective conversion of this renewable yet intermittent resource into a transportable and dispatchable chemical fuel may ensure the goal of a sustainable energy future. However, low conversion efficiencies, particularly with CO(2) reduction, as well as utilization of precious materials have limited the practical generation of solar fuels. By using a solar cavity-receiver reactor, we combined the oxygen uptake and release capacity of cerium oxide and facile catalysis at elevated temperatures to thermochemically dissociate CO(2) and H(2)O, yielding CO and H(2), respectively. Stable and rapid generation of fuel was demonstrated over 500 cycles. Solar-to-fuel efficiencies of 0.7 to 0.8% were achieved and shown to be largely limited by the system scale and design rather than by chemistry.
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            The Fischer–Tropsch process: 1950–2000

            Mark E Dry (2002)
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              A review and comparative evaluation of thermochemical water splitting cycles for hydrogen production

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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                Energy Conversion and Management
                Energy Conversion and Management
                Elsevier BV
                01968904
                October 2021
                October 2021
                : 245
                : 114528
                Article
                10.1016/j.enconman.2021.114528
                e686fbab-9cf4-49bf-b4d1-7180a332c8d7
                © 2021

                https://www.elsevier.com/tdm/userlicense/1.0/

                http://creativecommons.org/licenses/by/4.0/

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