Transport and turnstiles in multidimensional Hamiltonian mappings for unimolecular fragmentation: Application to van der Waals predissociation

The phase space for Hamiltonians of two degrees of freedom is usually divided into stochastic and integrable components. Even when well into the stochastic regime, integrable orbits may surround small stable regions or islands. The effect of these islands on the correlation function for the stochastic trajectories is examined. Depending on the value of the parameter describing the rotation number for the elliptic fixed point at the center of the island, the long-time correlation function may decay as t^-5 or exponentially, but more commonly it decays much more slowly (roughly as t^-1). As a consequence these small islands may have a profound effect on the properties of the stochastic orbits. In particular, there is evidence that the evolution of a distribution of particles is no longer governed by a diffusion equation.