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      C−N Bond Formation from a Masked High-Valent Copper Complex Stabilized by Redox Non-Innocent Ligands

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          Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis.

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            Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

            Copper-catalyzed Ullmann condensations are key reactions for the formation of carbon-heteroatom and carbon-carbon bonds in organic synthesis. These reactions can lead to structural moieties that are prevalent in building blocks of active molecules in the life sciences and in many material precursors. An increasing number of publications have appeared concerning Ullmann-type intermolecular reactions for the coupling of aryl and vinyl halides with N, O, and C nucleophiles, and this Minireview highlights recent and major developments in this topic since 2004.
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              High-valent organometallic copper and palladium in catalysis.

              Copper and palladium catalysts are critically important in numerous commercial chemical processes. Improvements in the activity, selectivity and scope of these catalysts could drastically reduce the environmental impact, and increase the sustainability, of chemical reactions. One rapidly developing strategy for achieving these goals is to use 'high-valent' organometallic copper and palladium intermediates in catalysis. Here we describe recent advances involving both the fundamental chemistry and the applications of these high-valent metal complexes in numerous synthetically useful catalytic transformations.
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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley-Blackwell
                14337851
                August 26 2016
                August 26 2016
                : 55
                : 36
                : 10712-10716
                Article
                10.1002/anie.201605132
                e973621e-1f7e-4ea2-bea5-c4497550fe8d
                © 2016

                http://doi.wiley.com/10.1002/tdm_license_1

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