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      Nonequilibrium fluctuations, fluctuation theorems, and counting statistics in quantum systems

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          Abstract

          Fluctuation theorems (FTs), which describe some universal properties of nonequilibrium fluctuations, are examined from a quantum perspective and derived by introducing a two-point measurement on the system. FTs for closed and open systems driven out of equilibrium by an external time-dependent force, and for open systems maintained in a nonequilibrium steady-state by nonequilibrium boundary conditions, are derived from a unified approach. Applications to fermion and boson transport in quantum junctions are discussed. Quantum master equations and Green's functions techniques for computing the energy and particle statistics are presented.

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          A nonequilibrium equality for free energy differences

          An expression is derived for the classical free energy difference between two configurations of a system, in terms of an ensemble of finite-time measurements of the work performed in parametrically switching from one configuration to the other. Two well-known equilibrium identities emerge as limiting cases of this result.
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            Equilibrium and nonequilibrium formalisms made unified

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              The Entropy Production Fluctuation Theorem and the Nonequilibrium Work Relation for Free Energy Differences

              There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability distribution of nonequilibrium systems. Another recently discovered far-from-equilibrium expression relates nonequilibrium measurements of the work done on a system to equilibrium free energy differences. In this paper, we derive a generalized version of the fluctuation theorem for stochastic, microscopically reversible dynamics. Invoking this generalized theorem provides a succinct proof of the nonequilibrium work relation.
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                Author and article information

                Journal
                22 November 2008
                2009-02-19
                Article
                10.1103/RevModPhys.81.1665
                0811.3717
                f366d45f-08dd-46a9-bd3f-5b7606c99f48

                http://arxiv.org/licenses/nonexclusive-distrib/1.0/

                History
                Custom metadata
                Rev. Mod. Phys. 81, 1665 (2009)
                Accepted in Rev. Mod. Phys. v2: Some references added and typos corrected
                cond-mat.stat-mech

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