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      Over-Stretching Tolerant Conductors on Rubber Films by Inkjet-Printing Silver Nanoparticles for Wearables

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          Abstract

          The necessity to place sensors far away from the processing unit in smart clothes or artificial skins for robots may require conductive wirings on stretchable materials at very low-cost. In this work, we present an easy method to produce wires using only commercially available materials. A consumer grade inkjet printer was used to print a wire of silver nanoparticles with a sheet resistance below 1 Ω/sq. on a non-pre-strained sheet of elastic silicone. This wire was stretched more than 10,000 times and was still conductive afterwards. The viscoelastic behavior of the substrate results in a temporarily increased resistance that decreases to almost the original value. After over-stretching, the wire is conductive within less than a second. We analyze the swelling of the silicone due to the ink’s solvent and the nanoparticle film on top by microscope and SEM images. Finally, a 60 mm long stretchable conductor was integrated onto wearables, and showed that it can bear strains of up to 300% and recover to a conductivity that allows the operation of an assembled LED assembled at only 1.8 V. These self-healing wires can serve as wiring and binary strain or pressure sensors in sportswear, compression underwear, and in robotic applications.

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          Most cited references35

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          Solvent compatibility of poly(dimethylsiloxane)-based microfluidic devices.

          This paper describes the compatibility of poly(dimethylsiloxane) (PDMS) with organic solvents; this compatibility is important in considering the potential of PDMS-based microfluidic devices in a number of applications, including that of microreactors for organic reactions. We considered three aspects of compatibility: the swelling of PDMS in a solvent, the partitioning of solutes between a solvent and PDMS, and the dissolution of PDMS oligomers in a solvent. Of these three parameters that determine the compatibility of PDMS with a solvent, the swelling of PDMS had the greatest influence. Experimental measurements of swelling were correlated with the solubility parameter, delta (cal(1/2) cm(-3/2)), which is based on the cohesive energy densities, c (cal/cm(3)), of the materials. Solvents that swelled PDMS the least included water, nitromethane, dimethyl sulfoxide, ethylene glycol, perfluorotributylamine, perfluorodecalin, acetonitrile, and propylene carbonate; solvents that swelled PDMS the most were diisopropylamine, triethylamine, pentane, and xylenes. Highly swelling solvents were useful for extracting contaminants from bulk PDMS and for changing the surface properties of PDMS. The feasibility of performing organic reactions in PDMS was demonstrated by performing a Diels-Alder reaction in a microchannel.
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            A highly stretchable, transparent, and conductive polymer

            A polymer is described that is conductive and stretchable, which can lead to electronics that can conform to the human body.
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              Highly conductive and stretchable silver nanowire conductors.

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                Author and article information

                Journal
                Polymers (Basel)
                Polymers (Basel)
                polymers
                Polymers
                MDPI
                2073-4360
                19 December 2018
                December 2018
                : 10
                : 12
                : 1413
                Affiliations
                [1 ]Institute for Nanoelectronics, Technical University of Munich, Theresienstr. 90, München 80333, Germany; andreas.albrecht@ 123456tum.de (A.A.); marco.bobinger@ 123456tum.de (M.B.); jf.salmeron@ 123456tum.de (J.F.S.); markus.becherer@ 123456tum.de (M.B.)
                [2 ]Institute for Cognitive Systems, Technical University of Munich, Karlstr. 45, München 80333, Germany; gordon@ 123456tum.de
                [3 ]Free University of Bozen-Bolzano, Universitätsplatz 1, Bozen-Bolzano 39100, Italy; paolo.lugli@ 123456unibz.it
                [4 ]Pervasive Electronics Advanced Research Laboratory (PEARL), Department of Electronics and Computer Technology, University of Granada, 18071 Granada, Spain
                Author notes
                [* ]Correspondence: arivadeneyra@ 123456ugr.es ; Tel.: +34-9582489
                Author information
                https://orcid.org/0000-0002-9813-4319
                https://orcid.org/0000-0002-9205-9477
                https://orcid.org/0000-0003-0770-8717
                https://orcid.org/0000-0002-2511-5643
                Article
                polymers-10-01413
                10.3390/polym10121413
                6401758
                fb997752-91e1-43ba-a908-b1bbd1d71d9a
                © 2018 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 05 November 2018
                : 14 December 2018
                Categories
                Article

                inkjet printing,printed electronics,silver nanoparticles,stretchable,wearables

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