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      Application of the Metal Reflector for Redistributing the Focusing Intensity of SPPs

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          Abstract

          The near-field photolithography system has attracted increasing attention in the micro- and nano-manufacturing field, due to the high efficiency, high resolution, and the low cost of the scheme. Nevertheless, the low quality of the nano-patterns significantly limits the industrial application of this technology. Theoretical calculations showed that the reason for the poor nano-patterns is the sharp attenuation of the surface plasmon polaritons (SPPs) in the photoresist layer. The calculation results suggest that the waveguide mode, which is composed of the chromium-equivalent dielectric layer-aluminum, can facilitate the energy flux density distribution in the photoresist layer, resulting in the enhancement of the field intensity of SPPs in the photoresist layer. This reduces the linewidth of nano-patterns, while it enhances the pattern steepness. Eventually, the focusing energy of the photoresist layer can be improved. The finite-difference time-domain method was employed to simulate and verify the theoretical results. It is found that for the rotational near-field photolithography with 355 nm laser illumination, the linewidths of the nano-patterns with and without the aluminum reflector are 17.54 nm and 65.51 nm, respectively. The robustness of the experimental results implies that the application of the aluminum reflector enhances the focusing effect in the photoresist, which can broaden the application of the near-field photolithography.

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          Surface Plasmons in Thin Films

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            Nanomaterials enhanced surface plasmon resonance for biological and chemical sensing applications.

            The main challenge for all electrical, mechanical and optical sensors is to detect low molecular weight (less than 400 Da) chemical and biological analytes under extremely dilute conditions. Surface plasmon resonance sensors are the most commonly used optical sensors due to their unique ability for real-time monitoring the molecular binding events. However, their sensitivities are insufficient to detect trace amounts of small molecular weight molecules such as cancer biomarkers, hormones, antibiotics, insecticides, and explosive materials which are respectively important for early-stage disease diagnosis, food quality control, environmental monitoring, and homeland security protection. With the rapid development of nanotechnology in the past few years, nanomaterials-enhanced surface plasmon resonance sensors have been developed and used as effective tools to sense hard-to-detect molecules within the concentration range between pmol and amol. In this review article, we reviewed and discussed the latest trend and challenges in engineering and applications of nanomaterials-enhanced surface plasmon resonance sensors (e.g., metallic nanoparticles, magnetic nanoparticles, carbon-based nanomaterials, latex nanoparticles and liposome nanoparticles) for detecting "hard-to-identify" biological and chemical analytes. Such information will be viable in terms of providing a useful platform for designing future ultrasensitive plasmonic nanosensors.
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              Plasmonic field enhancement and SERS in the effective mode volume picture.

              The controlled creation of nanometric electromagnetic field confinement via surface plasmon polariton excitations in metal/insulator/metal heterostructures is described via the concept of an effective electromagnetic mode volume Veff. Extensively used for the description of dielectric microcavities, its extension to plasmonics provides a convenient figure of merit and allows comparisons with dielectric counterparts. Using a one-dimensional analytical model and three-dimensional finite-difference time-domain simulations, it is shown that plasmonic cavities with nanometric dielectric gaps indeed allow for physical as well as effective mode volumes well below the diffraction limit in the gap material, despite significant energy penetration into the metal. In this picture, matter-plasmon interactions can be quantified in terms of quality factor Q and Veff, enabling a resonant cavity description of surface enhanced Raman scattering.
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                Author and article information

                Journal
                Nanomaterials (Basel)
                Nanomaterials (Basel)
                nanomaterials
                Nanomaterials
                MDPI
                2079-4991
                13 May 2020
                May 2020
                : 10
                : 5
                : 937
                Affiliations
                [1 ]College of Mechanical and Electronic Engineering, China University of Petroleum, Qingdao 266580, China; xupfupc@ 123456163.com (P.X.); linzhongwen_upc@ 123456163.com (Z.L.); lijing85@ 123456upc.edu.cn (J.L.)
                [2 ]School of Mechanical Engineering, Dalian University of Technology, Dalian 116024, China
                [3 ]College of New Energy, China University of Petroleum, Qingdao 266580, China; Ying1606050115@ 123456163.com
                [4 ]State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China; mengyg@ 123456tsinghua.edu.cn
                Author notes
                [* ]Correspondence: jijiaxin@ 123456upc.edu.cn
                Author information
                https://orcid.org/0000-0002-1349-6864
                https://orcid.org/0000-0001-5605-6394
                Article
                nanomaterials-10-00937
                10.3390/nano10050937
                7279234
                32413982
                fbd8d339-b207-4f9b-a9ba-364282899957
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 20 February 2020
                : 04 May 2020
                Categories
                Article

                metal reflector,energy flux density,energy redistribution,rotational near-field photolithography

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