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      The Origin of Carbonate Veins Within the Sedimentary Cover and Igneous Rocks of the Cocos Ridge: Results From IODP Hole U1414A

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          Abstract

          Carbonate veins in the igneous basement and in the lithified sedimentary cover of the Cocos Ridge at International Ocean Discovery Program (IODP) Hole 344‐U1414A reveal the hydrologic system and fluid‐rock interactions. IODP Hole 344‐U1414A was drilled on the northern flank of the Cocos Ridge and is situated 1 km seaward from the Middle America Trench offshore Costa Rica. Isotopic and elemental compositions were analyzed to constrain the fluid source of the carbonate veins and to reveal the thermal history of Hole 344‐U1414A. The formation temperatures (oxygen isotope thermometer) of the carbonate veins in the lithified sedimentary rocks range from 70 to 92 °C and in the basalt from 32 to 82 °C. 87Sr/ 86Sr ratios of the veins in the altered Cocos Ridge basalt range between 0.707307 and 0.708729. The higher ratios are similar to seawater strontium ratios in the Neogene. 87Sr/ 86Sr ratios lower 0.7084 indicate exchange of Sr with the igneous host rock. The calcite veins hosted by the sedimentary rocks are showing more primitive 87Sr/ 86Sr ratios <0.706396. The isotopic compositions indicate seawater, modified into a hydrothermal fluid by subsequent heating, as the main fluid source. Low‐temperature alteration and the presence of a high‐temperature fluid resulted in different carbonate precipitates forming up to several cm thick veins. The geochemical data combined with age data of the sedimentary rocks suggest intraplate seamount volcanism in the area between the Galapagos hot spot and the Cocos Island as an additional heating source, after the formation of the Cocos Ridge at the Galapagos hot spot.

          Key Points

          • Oxygen and strontium isotope ratios of carbonate veins suggest seawater and hydrothermally modified seawater as fluid source

          • Isotopic and elemental compositions reveal fluid‐rock interactions in the Cocos Ridge basalt and in the lithified sedimentary rocks

          • Intraplate seamount volcanism in the area between the Galapagos hot spot and the Cocos Island acted as an additional heating source

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                Author and article information

                Contributors
                jennifer.brandstaetter@uni-graz.at
                Journal
                Geochem Geophys Geosyst
                Geochem Geophys Geosyst
                10.1002/(ISSN)1525-2027
                GGGE
                Geochemistry, Geophysics, Geosystems : G(3)
                John Wiley and Sons Inc. (Hoboken )
                1525-2027
                11 October 2018
                October 2018
                : 19
                : 10 ( doiID: 10.1002/ggge.v19.10 )
                : 3721-3738
                Affiliations
                [ 1 ] Institute of Earth Sciences, NAWI Graz Geocenter University of Graz Graz Austria
                [ 2 ] Department of Geology Lund University Lund Sweden
                [ 3 ] Ocean and Earth Science, National Oceanography Centre Southampton University of Southampton Southampton England, UK
                Author notes
                [*] [* ] Correspondence to: J. Brandstätter,

                jennifer.brandstaetter@ 123456uni-graz.at

                Author information
                http://orcid.org/0000-0002-8983-1104
                http://orcid.org/0000-0002-0071-8261
                http://orcid.org/0000-0001-5424-3540
                http://orcid.org/0000-0002-2130-2759
                http://orcid.org/0000-0002-4416-8409
                Article
                GGGE21702 2018GC007729
                10.1029/2018GC007729
                6282762
                30546270
                fbfb05ba-848a-4482-88b4-844f5b405b69
                ©2018. The Authors.

                This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

                History
                : 04 June 2018
                : 04 September 2018
                : 13 September 2018
                Page count
                Figures: 8, Tables: 4, Pages: 18, Words: 8180
                Funding
                Funded by: Austrian Science Fund
                Award ID: FWF‐P‐26634‐N29
                Categories
                Biogeosciences
                Isotopic Composition and Chemistry
                Geochemistry
                Alteration and Weathering Processes
                Stable Isotope Geochemistry
                Major and Trace Element Geochemistry
                Marine Geochemistry
                Mid‐oceanic Ridge Processes
                Mineralogy and Petrology
                Alteration and Weathering Processes
                Mid‐oceanic Ridge Processes
                Oceanography: Biological and Chemical
                Stable Isotopes
                Marine Inorganic Chemistry
                Nutrients and Nutrient Cycling
                Marine Organic Chemistry
                Volcanology
                Mid‐oceanic Ridge Processes
                Research Article
                Research Articles
                Custom metadata
                2.0
                ggge21702
                October 2018
                Converter:WILEY_ML3GV2_TO_NLMPMC version:version=5.5.3 mode:remove_FC converted:06.12.2018

                cocos ridge,iodp,carbonate veins,isotope geochemistry,elemental composition,fluid‐rock interaction

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