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Reductive annulations of arylidene malonates with unsaturated electrophiles using photoredox/Lewis acid cooperative catalysis†
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6 February 2019
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Abstract
Abstract
A cooperative Lewis acid/photocatalytic reduction of salicylaldehyde-derived arylidene malonates provides access to a versatile, stabilized radical anion enolate. Using these unusual umpolung operators, we have developed a novel route to access densely functionalized carbo- and heterocycles through a radical annulation addition pathway.
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†Electronic supplementary information (ESI) available. CCDC 1835356. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc00302a