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      Deuterium Chemistry in the Young Massive Protostellar Core NGC 2264 CMM3

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          Abstract

          In this work we present the first attempt of modelling the deuterium chemistry in the massive young protostellar core NGC 2264 CMM3. We investigated the sensitivity of this chemistry to the physical conditions in its surrounding environment. The results showed that deuteration, in the protostellar gas, is affected by variations in the core density, the amount of gas depletion onto grain surfaces, the CR ionisation rate, but it is insensitive to variations in the H\(_2\) ortho-to-para ratio. Our results, also, showed that deuteration is often enhanced in less-dense, partially depleted (\(<\) 85\%), or cores that are exerted to high CR ionisation rates (\(\ge\) 6.5 \(\times\) 10\(^{-17}\) s\(^{-1}\) ). However, in NGC 2264 CMM3, decreasing the amount of gas depleted onto grains and enhancing the CR ionisation rate are often overestimating the observed values in the core. The best fit time to observations occurs around (1 - 5) \(\times\) 10\(^4\) yrs for core densities in the range (1 - 5) \(\times\) 10\(^6\) cm\(^{-3}\) with CR ionisation rate between (1.7 - 6.5)\(\times\) 10\(^{-17}\) s\(^{-1}\). These values are in agreement with the results of the most recent theoretical chemical model of CMM3, and the time range of best fit is, also, in-line with the estimated age of young protostellar objects. We conclude that deuterium chemistry in protostellar cores is: (i) sensitive to variations in the physical conditions in its environment, %(ii) deuteration in the protostellar gas is (ii) insensitive to changes in the H\(_2\) ortho-to-para ratio. %, but is sensitive to these variations in the dark cloud phase. We also conclude that the core NGC 2264 CMM3 is in its early stages of chemical evolution with an estimated age of (1 - 5) \(\times\) 10\(^4\) yrs.

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          Submillimeter continuum observations of Rho Ophiuchi A - The candidate protostar VLA 1623 and prestellar clumps

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            Complex Organic Interstellar Molecules

            Of the over 150 different molecular species detected in the interstellar and circumstellar media, approximately 50 contain 6 or more atoms. These molecules, labeled complex by astronomers if not by chemists, all contain the element carbon and so can be called organic. In the interstellar medium, complex molecules are detected in the denser sources only. Although, with one exception, complex molecules have only been detected in the gas phase, there is strong evidence that they can be formed in ice mantles on interstellar grains. The nature of the gaseous complex species depends dramatically on the source where they are found: in cold, dense regions they tend to be unsaturated (hydrogen-poor) and exotic, whereas in young stellar objects, they tend to be quite saturated (hydrogen-rich) and terrestrial in nature. Based on both their spectra and chemistry, complex molecules are excellent probes of the physical conditions and history of the sources where they reside. Because they are detected in young stellar objects, complex molecules are expected to be common ingredients for new planetary systems. In this review, we discuss both the observation and chemistry of complex molecules in assorted interstellar regions in the Milky Way.
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              The chemical composition of the Sun

              The solar chemical composition is an important ingredient in our understanding of the formation, structure and evolution of both the Sun and our solar system. Furthermore, it is an essential reference standard against which the elemental contents of other astronomical objects are compared. In this review we evaluate the current understanding of the solar photospheric composition. In particular, we present a re-determination of the abundances of nearly all available elements, using a realistic new 3-dimensional (3D), time-dependent hydrodynamical model of the solar atmosphere. We have carefully considered the atomic input data and selection of spectral lines, and accounted for departures from LTE whenever possible. The end result is a comprehensive and homogeneous compilation of the solar elemental abundances. Particularly noteworthy findings are significantly lower abundances of carbon, nitrogen, oxygen and neon compared with the widely-used values of a decade ago. The new solar chemical composition is supported by a high degree of internal consistency between available abundance indicators, and by agreement with values obtained in the solar neighborhood and from the most pristine meteorites. There is, however, a stark conflict with standard models of the solar interior according to helioseismology, a discrepancy that has yet to find a satisfactory resolution.
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                Author and article information

                Journal
                11 December 2017
                Article
                10.1007/s10509-017-3232-7
                1712.04096
                fd31af0b-f9f2-4211-9226-b8ff4e49bed4

                http://arxiv.org/licenses/nonexclusive-distrib/1.0/

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                Custom metadata
                29 pages, 6 figures, Accepted in Astrophysics and Space Science, 2017
                astro-ph.SR astro-ph.GA

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