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      Metal–organic frameworks and their derived nanostructures for electrochemical energy storage and conversion

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          Abstract

          This review presents a summary of recent progress and strategies in fabricating MOF-based nanostructures for electrochemical applications.

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          Most cited references206

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          What Are Batteries, Fuel Cells, and Supercapacitors?

          Martin Winter, Ralph J Brodd (2004)
          Article 0 comments Cited 1218 times – based on 0 reviews     Review now
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            Materials for fuel-cell technologies.

            B. Steele, A. Heinzel (2001)
            Fuel cells convert chemical energy directly into electrical energy with high efficiency and low emission of pollutants. However, before fuel-cell technology can gain a significant share of the electrical power market, important issues have to be addressed. These issues include optimal choice of fuel, and the development of alternative materials in the fuel-cell stack. Present fuel-cell prototypes often use materials selected more than 25 years ago. Commercialization aspects, including cost and durability, have revealed inadequacies in some of these materials. Here we summarize recent progress in the search and development of innovative alternative materials.
            Article 0 comments Cited 1069 times – based on 0 reviews     Review now
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              High-performance electrocatalysts for oxygen reduction derived from polyaniline, iron, and cobalt.

              Gang Wu, Karren More, Christina Johnston … (2011)
              The prohibitive cost of platinum for catalyzing the cathodic oxygen reduction reaction (ORR) has hampered the widespread use of polymer electrolyte fuel cells. We describe a family of non-precious metal catalysts that approach the performance of platinum-based systems at a cost sustainable for high-power fuel cell applications, possibly including automotive power. The approach uses polyaniline as a precursor to a carbon-nitrogen template for high-temperature synthesis of catalysts incorporating iron and cobalt. The most active materials in the group catalyze the ORR at potentials within ~60 millivolts of that delivered by state-of-the-art carbon-supported platinum, combining their high activity with remarkable performance stability for non-precious metal catalysts (700 hours at a fuel cell voltage of 0.4 volts) as well as excellent four-electron selectivity (hydrogen peroxide yield <1.0%).
              Article 0 comments Cited 1026 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Journal ID (publisher-id): EESNBY
                Title: Energy Environ. Sci.
                Abbreviated Title: Energy Environ. Sci.
                Publisher: Royal Society of Chemistry (RSC)
                ISSN (Print): 1754-5692
                ISSN (Electronic): 1754-5706
                Publication date Created: 2015
                Publication date (Print): 2015
                Volume: 8
                Issue: 7
                Pages: 1837-1866
                Article
                DOI: 10.1039/C5EE00762C
                SO-VID: fe7bf761-8e47-4abe-8c62-9629be9b807f
                Copyright © © 2015
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